History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Proust is the discoverer of what is now styled “the law of constant
proportion,” which states that the same body is invariably composed
of the same elements, united in the same proportion. He was a skilful
analyst, and made numerous analyses of minerals; and he was one of the
earliest to undertake a systematic study of metallic salts of organic
acids.
CHAPTER IX
THE ATOMIC THEORY
The opening years of the nineteenth century were made memorable by the
promulgation of the atomic theory by John Dalton. The enunciation of
this theory, which affords a simple and adequate explanation of the
fundamental laws of chemical combination, marks an epoch in the history
of chemistry.
It may be desirable to trace, as briefly as possible, the successive
steps which led up to the generalisation which more than any other
has served to stamp chemistry as an exact science. That matter was
_discrete_—that is, that it was not continuous, but was composed of
ultimate particles—was, as already stated, imagined by the ancients,
and was part of the philosophy of Leukippus, Demokritus, and
Leucretius. But this supposition, although favoured by Newton and other
thinkers, had little or no scientific basis prior to the middle of the
eighteenth century. From that time onward a variety of chemical facts
gradually accumulated, many of which at the time of their discovery
had no obvious connection with pre-existing facts. It was reserved for
Dalton to point out how an extension and more precise definition of
the old doctrine would suffice to connect and explain them.
The first germ of an atomic theory based on chemical fact may be traced
in the observation of =Toburn Bergmann= (b. 1735, d. 1784), Professor
of Chemistry at Upsala, that neutral solutions of certain metals in
contact with other metals gave a precipitate without the neutrality of
the solution being disturbed, and without gas being evolved. One metal
had simply replaced the other in solution. Bergmann thus incidentally
discovered the fact of the chemical equivalence of metals. He was
of opinion, however, that the phenomenon meant a transference of
phlogiston from one metal to another, and that the process might be
made a mode of determining the relative amount of phlogiston in various
metals. Lavoisier extended Bergmann’s observations, and sought to show,
in effect, that the process afforded a means of determining the amounts
of the several metals which combined with one and the same quantity
of oxygen. But neither Bergmann nor Lavoisier really grasped the idea
of equivalence as we understand it to-day. It began to be appreciated
as the result of the work of =Jeremiah Benjamin Richter= (b. 1762,
d. 1807) and of =G. E. Fischer= on the mutual action of salts in
solutions, and on the determinations of the amounts of acid and bases
which respectively combine with one another. Methods of measurement of
the proportions in which substances combine were grouped by Richter
under the term _Stochiometry_.
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