History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
However desirable it may be in the interests of history to indicate
the sequence of the surmises and facts which preceded the formulation
of the atomic theory, it is very doubtful whether Dalton was, to any
material extent, influenced by them. A self-educated man of lowly
origin, sturdily independent and highly original, he was accustomed
to rely upon his own faculty of observation and experiment for his
facts, and upon his own intellectual powers and mental energy for their
interpretation.
=John Dalton=, the son of a Quaker hand-loom weaver, was born at
Eaglesfield, in Cumberland, in 1766. While still a boy he took to
school-teaching, and acquired, in his leisure and by his own exertions,
a competent knowledge of mathematics and physical science. In 1793 he
was called to give instruction in mathematics, natural philosophy, and
chemistry at the Manchester New College, the Nonconformist academy—now
moved from Warrington—in which Priestley had formerly lectured. Here
he remained six years, leaving the college to take up an independent
position as a private tutor, so as to enable him the more freely to
pursue his scientific inquiries. In 1800 he became Secretary of the
Philosophical Society of Manchester, and remained connected, as an
official, with that institution until his death in 1844. The greater
number of his scientific communications were published by that society.
In the outset of his scientific career he was attracted to meteorology;
and it was probably its problems which led him in the first place to
experiment, and to speculate on the physical constitution of gases.
In the course of these observations he was led to the discovery
of the law of thermal expansion of gases, with which his name is
now generally associated. His speculations concerning the physical
constitution of gaseous substances, arising from the contemplation of
gaseous phenomena, led him to the conception that a gas is composed
of particles that repel one another with a force decreasing as the
distance of their centres from each other; and it is probable that in
this manner he familiarised himself with the idea of the existence of
atoms. His first insight into the laws of the chemical combination of
these atoms seems to have originated from his discovery that, when
two substances unite in different proportions, these proportions may
be expressed in simple multiples of whole numbers. Thus he found,
on examining the composition of marsh gas and of ethylene, both
hydrocarbons, that for the same weight of hydrogen there was twice the
amount of carbon in ethylene that there was in marsh gas. He then
examined the oxides of nitrogen, and found a similar regularity to
hold good in these compounds. Some time prior to the autumn of 1803
Dalton was led to the supposition that these regularities could be
satisfactorily explained by the assumption that matter is composed
of atoms having sizes and weights differing with each substance, but
Public-domain text, read in full here on John Shaqi.
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