History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
of identical weight and size for any particular substance, and that
chemical combination consists in the approximation of these atoms. This
simple hypothesis explained all the facts then known. It explained the
constancy in the chemical composition of substances, which may be said
to have been established by Proust, and which is now formulated as the
Law of Constant Proportion—that the same body is invariably composed
of the same elements, united in the same proportion. It explained also
the fact discovered by Dalton that, when an element unites with another
in different proportions, the higher proportions are multiples of the
lowest—now formulated as the Law of Multiple Proportion. It further
explained the fact, which may be said to have been foreshadowed by
Richter, that when two bodies, A and B, separately combine with a third
body, C, the proportions of A and B which unite with C are measures or
multiples of the proportions in which A and B combine together. This
is known as the Law of Reciprocal Proportion.
[Illustration: JOHN DALTON.
From a painting by B. R. Faulkner in the possession of the Royal
Society]
Dalton’s theory was first made generally known by Thomas Thomson, in
the third edition of his _System of Chemistry_, published in 1807, and
was employed by Thomson in his paper on “The Oxalates of Strontium,”
published the same year in the _Philosophical Transactions_. The first
printed account by Dalton himself is contained in Part I. of his _New
System of Chemical Philosophy_, published in 1808, the substance of
which had been previously given in a course of lectures at the Royal
Institution, London, and subsequently repeated in Edinburgh and Glasgow.
The statement of his theory is contained in chapter iii. of this work,
under the heading “Of Chemical Synthesis,” and is accompanied by a
plate and explanation, of which a facsimile is given on pp. 130–1.
The facts upon which Dalton based his theory are incontrovertible; but
Dalton’s explanation of them was not universally accepted at the time
he gave it. Davy, who, of course, was familiar with the conception
of atoms as part of the Newtonian philosophy, objected to the term
“atomic weight” introduced by Dalton, and suggested the expression
“combining proportion”; and Wollaston, for similar reasons, proposed
the term “equivalent,” as denoting the constant quantity with which
bodies went in and out of combination. There is no doubt that the use
of these terms retarded the general acceptance of Dalton’s doctrine,
and, moreover, brought into the science a confusion which was not
finally dispelled, as we shall see, until during the second half of the
century.
[Illustration: ELEMENTS
_Simple_
_Binary_
_Ternary_
_Quaternary_
_Quinquenary_ & _Sextenary_
_Septenary_]
The illustration on the preceding page contains the arbitrary marks
or signs chosen to represent the several chemical elements or
ultimate particles.
Public-domain text, read in full here on John Shaqi.
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