History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
An atom of nitrate of ammonia, 1 nitric acid
+ 1 ammonia + 1 water 33
37. An atom of sugar, 1 alcohol + 1 carbonic acid 35
Dalton’s estimations of the relative weights of the atoms, or, to use
Davy’s phrase, the values of their combining proportions, were, as
might be expected, very rough approximations to the truth. This arose
partly from inadequate experimental data, and partly from uncertainty
as to the relative number of the constituent atoms which made up a
compound. Neither Dalton nor his immediate successors had any rational
or consistent method of determining the latter point. The view taken of
the composition of the compound decided what particular multiples or
sub-multiples of the values of the atomic weights of its constituents
were to be adopted. As Dalton, in many cases, had no real criterion to
guide him, he made the simplest possible assumptions; but these might
or might not be valid; and subsequent experience showed that in some
cases they were erroneous.
It was, however, generally recognised that these atomic weights,
combining proportions, or equivalents, as they were for a time
indifferently termed, were chemical constants of the highest
importance, both to the scientific chemist, who, apart from their
theoretic interest, had need of them in the course of quantitative
analysis, and to the manufacturing chemist, who required them for
the intelligent exercise of his operations; and accordingly a number
of chemists, very shortly after the promulgation of Dalton’s theory,
attempted to determine their values with all possible precision. Chief
among these was the Swedish chemist Berzelius, to whom science was
indebted for a series of estimations of atomic weights, which were long
regarded as models of quantitative accuracy, and stamped their author
as the greatest master of determinative chemistry of his age.
=Jöns Jakob Berzelius=, the son of a schoolmaster, was born near
Linköping, in East Gothland, Sweden, in 1779. Entering Upsala with
a view to the profession of medicine, he was attracted, under the
influence of Afzelius—or, rather, in spite of it—to the study of
chemistry, and, later, of voltaic electricity, then in its infancy.
While holding a number of minor appointments as a teacher of medicine,
pharmacy, physics, and chemistry, he was elected, in 1808, a member
of the Swedish Academy of Sciences, of which he became President in
1810. In 1818 he was made permanent Secretary of the Academy, and, by
means of a yearly subsidy, was enabled to devote himself wholly to
experimental science. He was ennobled in 1818, and on the occasion of
his marriage, in 1835, was created a baron of the Scandinavian kingdom.
He died in 1848.
Public-domain text, read in full here on John Shaqi.
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