History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Berzelius occupies a pre-eminent position in the history of chemistry,
and during a considerable portion of his lifetime exercised an almost
unassailable authority as a chemical philosopher. He is distinguished
as an experimenter, as a discoverer, as a critic and interpreter,
and as a lawgiver. His contributions to chemical knowledge range
over every department of the science. He shares with Davy the honour
of having established the fundamental laws of electro-chemistry.
His experimental work on the atomic weights of the elements—the
great work of his life—was of supreme importance at this particular
period of the development of chemistry: it served not only to give
precision to, and enhance the significance and value of, Dalton’s
generalisation, but it furnished chemists, for the first time, with
a set of constants, ascertained with the highest exactitude of which
operative chemistry was then capable, thereby contributing to the
expansion of quantitative analysis, and to a more exact knowledge of
the composition of substances. Berzelius, indeed, was an analyst of the
first rank—conscientious, patient, and painstaking; an ingenious and
skilful manipulator; inventive and resourceful. What determinative
chemistry owes to his labours, and not less to his example, is obvious
from even the most superficial examination of its literature during the
first third of the last century.
As a discoverer, Berzelius first made known the existence of _cerium_
(1803), of _selenium_ (1818), and of _thorium_ (1828); and he prepared
and investigated a large number of their combinations. He isolated
_silicon_ (1823), _zirconium_ (1824), _tantalum_ (1824), and studied
the compounds of _vanadium_, discovered by his countryman Sefström.
He largely extended our knowledge of groups of substances in which
sulphur replaces oxygen; investigated compounds of fluorine (1824),
platinum (1828), and tellurium (1831–1833), and made many analyses of
minerals, meteorites, and mineral-waters. He discovered _racemic acid_
and investigated the ferrocyanides. It was his investigation of racemic
acid—which has the same percentage composition as tartaric acid—that
first enabled him to grasp the conception of _isomerism_, a term which
we owe to him, and of _metamerism_ and _polymerism_. He was the first
to study the phenomena of contact-actions, which he comprehended under
the term _catalysis_.
[Illustration: JÖNS JAKOB BERZELIUS.
From a painting by J. G. Sandberg.]
As an author his literary activity was astonishing. His new system of
mineralogy marks an epoch in the history of that branch of science. His
text-book on chemistry was long the leading manual, and went through
many editions, being constantly revised by him. His annual reports on
the progress of physics and chemistry extended to twenty-seven volumes
and constitute a monument to his industry, thoroughness, perspicacity,
and critical ability.
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