History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Although holding no university appointment, and with a laboratory of
the most modest dimensions and character, Berzelius, exercised great
influence as a teacher. Some of the most notable chemists of the last
century, such as Heinrich and Gustav Rose, Dulong, Mitscherlich,
Wöhler, Chr. Gmelin, and Mosander, were among his pupils; and many of
them have testified to his stimulating power as an investigator of
nature, and to his merits as a worthy, genial man.
The reasonableness of Dalton’s conjecture received further support
from the discovery by Gay Lussac in 1808, that gases always combine
in simple proportions by volume, and that the volume of the gaseous
product formed, when measured under comparable conditions of
temperature and pressure, stands in a simple relation to the volumes
of the constituents. The law of pressure discovered by Boyle, that
of thermal expansion by Dalton, and of volumes by Gay Lussac (which,
it ought to be stated, was previously and independently made by
Dalton), are explained on the assumption that equal numbers of the
particles—either as simple particles or as compound particles—are
present in the same volume of the gas. This method of explanation was
first clearly stated by the Italian physicist =Avogadro= in 1811, but
its significance, as will be seen subsequently, was not appreciated
until half a century later.
As the values for the atomic weights gradually became more exact,
speculations arose as to the significance of the numerical relations
which were observed to exist among them. In 1815 =William Prout= threw
out the supposition that the atomic weights of the gaseous elements
are multiples by whole numbers of that of hydrogen. Extended into a
generalisation, this might be held to indicate that all kinds of matter
are so many forms of a primordial substance. Subsequent inquiry showed
that Prout’s “Law,” as it is sometimes called, was not tenable in its
original form. Certain elements, it was conclusively proved, had atomic
weights which were not whole numbers. Dumas subsequently modified the
law, after a redetermination of a large number of atomic weights,
by assuming that the substance common to the so-called elements had
a lower atomic weight than unity. Although there are a considerable
number of elements whose atomic weights, based upon the most
accurate determinations, are remarkably close to whole numbers, the
investigations of Stas and others afford no valid reason for believing
that Prout’s hypothesis, and the underlying supposition to which it has
been held to point, are justified by experimental evidence.
CHAPTER X
THE BEGINNINGS OF ELECTRO-CHEMISTRY
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