History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
A necessary consequence of these views was that every compound was to
be considered as made up of two parts in electrically different states.
Thus baryta, consisted of a combination of the electro-positive barium,
combined with the electro-negative oxygen; it combined with sulphuric
oxide because the preponderating positive electricity it contained met
with the negative electricity which prevailed in the sulphuric oxide.
Generalising, it may be said that the basic oxides are invariably
the positive constituents of salts, whereas the acid oxides are the
negative constituents, as proved by the mode in which the two kinds of
oxides separated at the poles on electrolysis. Barium sulphate, then,
was to be regarded as made up of two entities—BaO and SO3—and hence was
to be called sulphate of baryta. Berzelius extended this conception
in order to explain the formation of double salts—such, for example,
as potash alum, which he regarded as a binary compound of positive
potassium sulphate and negative aluminium sulphate, each of which,
in its turn, could be resolved into an acidic and a basic oxide of
opposite electricities.
The dualistic notions of Berzelius led him to the construction of
a system of chemical nomenclature and notation which, in its main
features, has persisted to this day, and is universally current, with
certain modifications, in modern chemical literature. We owe to him
the grouping of the elements into metals and metalloids, and also our
present system of symbolic notation, whereby even complicated chemical
reactions may be expressed in a concise and intelligible manner.
Chemical symbols were used by the alchemists; but Berzelius first
suggested that a chemical symbol should not only represent the element
to which it refers, but also its relative atomic weight. Chemical
equations became quantitative as well as qualitative expressions of
the facts they denote. Such equations implicitly assumed that, to
use Davy’s words, chemistry had passed under the dominion of the
mathematical sciences. Professed mathematicians were, however, slow to
recognise that the phenomena of chemical action were capable of formal
mathematical treatment. Davy relates that on speaking to Laplace of
the atomic theory in chemistry, and expressing his belief that the
science would ultimately be referred to mathematical laws similar to
those he had so profoundly and successfully established with respect
to the mechanical properties of matter, the idea was treated in a tone
bordering on contempt.
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