History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Berzelius’s electro-chemical system, and the dualistic ideas associated
with it, were of considerable service when applied to the inorganic
branch of the science; but attempts to fit them to the facts of organic
chemistry, which began to accumulate rapidly after the first quarter of
the century, failed. Its inadequacy as a comprehensive generalisation
became more and more manifest, and it eventually fell. In fact, it may
be said to have received its death-blow by Davy’s discovery of the
elementary nature of chlorine, and by the recognition of the fact that
the acids do not necessarily contain oxygen. Davy and, later, Dulong
made it obvious that, if any one element was to be regarded as the
acidifying principle, it was hydrogen, and not oxygen; and, in a sense,
this view ultimately prevailed in the recognition of the acids as salts
of hydrogen.
In France the study of electro-chemistry was undertaken by Gay Lussac
and Thénard, largely owing to the action of the Emperor Napoleon,
who furnished the funds for the construction of a powerful galvanic
battery. The results were published, in 1811, under the title,
_Recherches Physico-Chimiques, faites sur la Pile_, etc. Gay Lussac,
whose name has already been mentioned as one of the discoverers of
the Law of Combination of Gases, played a considerable part in the
history of chemistry at this period. He was one of the earliest to
appreciate the importance of Dalton’s generalisation, and to point
out the significance of his own discovery in strengthening it. He was
probably led, in the first instance, to the recognition of the law of
gaseous combination by Berthollet’s work on the volumetric composition
of ammonia gas, and by his own discovery—made in 1805, in conjunction
with Humboldt, in the course of their analysis of atmospheric air—that
one volume of oxygen combined with exactly two volumes of hydrogen to
form water. The regularities thus indicated he found to be general: all
gases which are capable of chemical union combine in simple proportions
by volume, and the volume of the product, if a gas, always stands in
some simple relation to the volumes of the constituents.
=Joseph Louis Gay Lussac= was born in 1778, at Saint Leonard, studied
chemistry in Paris, and was associated in chemical inquiry with
Berthollet. As Eleve-Ingenieur in the École Nationale des Ponts et
des Chaussées he began the experimental work in physics and chemistry
upon which his fame rests. In 1804 he undertook, with Biot, a series
of balloon ascents for the purpose of investigating the physics and
chemistry of the upper regions of the atmosphere. In 1806 he became
Professor of Chemistry at the École Polytechnique, and in 1832
Professor at the Jardin des Plantes. He was one of the chief assayers
of the French Mint, and, as member of many commissions, exerted
considerable influence in official circles. He died in 1850.
Public-domain text, read in full here on John Shaqi.
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