History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
In 1834 Faraday made known the important fact that on passing the same
galvanic current through a number of electrolytes—water, hydrochloric
acid, solutions of metallic chloride—these were decomposed in such
manner that definite amounts of hydrogen or metal were separated at the
negative pole, and corresponding amounts of oxygen or chlorine were
evolved at the positive pole. These observations were comprehended
by Faraday under his “law of definite electrolytic action.” The
electro-chemical equivalents thus obtained were in some cases identical
with the atomic weights deduced by Berzelius; in others they were
not; but, nevertheless, when they differed, they stood in some simple
relation to the assumed atomic weight. The significance of Faraday’s
observation was not lost sight of, although his anticipation that the
determination of electro-chemical equivalents would be of use in fixing
atomic weights was not immediately appreciated. A clear distinction
between the _equivalent_, the _atom_, and the _molecule_ was not
then apprehended. As will be subsequently shown, it was only during
the latter half of the nineteenth century that the discrepancies and
inconsistencies thus revealed were definitely reconciled and cleared
up.
CHAPTER XI
THE FOUNDATIONS OF ORGANIC CHEMISTRY
As the horizon of chemistry widened and its operations extended, it
became necessary to treat its subject-matter methodically. Accordingly
attempts were made in the various systematic treatises which began to
appear in the seventeenth century to group its facts into an orderly
and rational arrangement. One of the earliest of such systematic
treatises was the _Cours de Chimie_ of Nicolas Lemery, published in
1675. Although this work was styled by Boerhaave “a tumultuary mass of
pharmaceutical processes, without any certain design or coherence,” it
is noteworthy as being the first of its kind to divide the science into
its present main branches of inorganic and organic chemistry.
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