History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Gay Lussac and Thénard were the first to devise a method of obtaining
potassium and sodium by a purely chemical process, whereby these
metals could be procured in far larger quantities than was at that
time possible by electrolytic means. They were thus enabled to make
use of the strong deoxidising power of these metals to effect a number
of reductions, notably that of boric oxide to _boron_. Gay Lussac and
Thénard were also the first to make known the existence of _boron
fluoride_. We further owe to Gay Lussac the discovery of _cyanogen_,
the first of the so-called compound radicals. He first prepared
ethyl iodide, investigated sulphovinic acid and grape sugar, studied
etherification and fermentation, etc. We are also indebted to him
for a method of determining vapour densities which proved of great
service in ascertaining the molecular weights of substances. He worked
on iodine and its compounds, discovered, with Welter, _thiosulphuric_
acid, and investigated fulminic acid in collaboration with Liebig.
Among his services to analytical chemistry were his method for the
analysis of gunpowder, his volumetric estimation of silver (wet silver
assay), chlorometric analysis, alkalimetry, etc. He devised the system
still in use in France for the estimation of alcohol in spirits of wine.
=Louis Jacques Thénard= was born in 1777 at Nogent-Sur-Seine, and was
a pupil of Vauquelin and of Berthollet. In 1797 he became _repétiteur_
at the Polytechnic School of Paris, and eventually its professor. He
subsequently occupied the chair of chemistry at the Collège de France,
and of the Faculty of Science of the University of Paris. He was
ennobled by Charles X. in 1824, and died at Paris in the eightieth year
of his age.
In addition to his work with Gay Lussac already mentioned, we owe
to Thénard the discovery of _hydrogen peroxide_ and _hydrogen
persulphide_. Together with Dulong he studied the catalytic action of
platinum on mixtures of oxygen and hydrogen. He investigated the fatty
acids, and worked on fermentation and on ether-formation; and he was
the first to isolate citric and malic acids. He also occupied himself
with the chemistry of bile, perspiration, albumen, the acids of urine
and milk, and with the theory of mordants.
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