History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
The contemporaries and immediate followers of Lavoisier were the
first to make a systematic attempt to elucidate the chemical nature
of organic products of animal origin. To this period belongs the work
of Fourcroy and Vauquelin on animal chemistry. Chevreul, a pupil of
Fourcroy worked on urine, adipocire, and the animal fats in the first
decade of the last century. Kirchhoff in 1811, discovered the method
of converting starch into sugar; and Döbereiner, in 1822, described
a method of preparing formic acid artificially. Dumas and Boullay,
in 1827–1828, prepared a number of new derivatives of ethyl alcohol;
and in 1834 Dumas and Peligot studied in like manner the chemistry of
methyl alcohol, and pointed out many analogies which their compounds
possessed, not only among themselves, but also to inorganic substances.
Although a considerable amount of information as to the existence,
modes of occurrence, and properties of bodies found in the animal
and vegetable kingdoms had been accumulated by the end of the first
quarter of the nineteenth century, no serious attempt was made to
study them systematically until after that period. In fact, they
were not even regarded as coming within the operations of laws
found to be applicable to the products of the inorganic world, by
the investigation, of which products, indeed, those laws had been
discovered.
Down to 1828 it was considered that inorganic and organic substances
were sharply differentiated by the circumstance that, whereas the
former might be prepared by artificial means, and even built up from
their elements by synthetic processes in the laboratory, the latter
could only be formed in the bodies of animals and plants as the result
of vital force. In that year Wöhler showed that urea, pre-eminently
a product of animal metabolism, could be prepared synthetically from
inorganic materials. Other instances of a similar kind were discovered
in rapid succession; and the idea that organic substances could alone
be formed by vital processes was proved to be invalid. Moreover, large
numbers of substances of a character analogous to those produced by
physiological action, but not known to occur in the animal or vegetable
kingdom, were prepared. There is, therefore, no absolute distinction to
be drawn between the chemistry of the inorganic and organic worlds.
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