History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
But the influence of molecular or atomic grouping in determining
the specific character of a substance is not confined to compounds.
The same phenomenon is observed to occur among the elements. It was
conclusively established by Lavoisier that the diamond and charcoal
are chemically the same thing—both forms of carbon. Scheele showed that
graphite was a third form of carbon. Phosphorus, sulphur, and oxygen
were subsequently shown to be each capable of existence in various
modifications. Instances of this character were grouped together in
1841 by Berzelius under the term _allotropy_.
The recognition of the fact of isomerism exerted a great influence
on the development of organic chemistry. It ultimately led to the
assumption that particular groups of elements or atomic complexes,
so-called _radicals_, were to be found in organic compounds—a
conception based originally on Gay Lussac’s discovery of _cyanogen_,
a combination of carbon and nitrogen, which was found to behave like
a simple substance, such as chlorine, and to give rise to compounds
analogous to the corresponding chlorides. This idea of the existence of
compound radicals was greatly strengthened by a memorable investigation
by Liebig and Wöhler, in 1832, on oil of bitter almonds and its
derivatives, in which they showed that these substances might be
represented as containing a special group or radical termed _benzoyl_,
which behaved like an element. The idea of groups of elements going
in and out of combination like a simple substance was not new to
chemists: there was not only the case of cyanogen, discovered by Gay
Lussac in 1815. The attempt had been made by Dumas and Boullay in
1828 to classify the derivatives of alcohol and ether as compounds
containing a common radical _etherin_. Gay Lussac had pointed out that
the vapour density of ethyl alcohol seemed to show that it consisted
of equal volumes of ethylene and water. Robiquet had also shown that
ethyl chloride might be assumed to be a compound of hydrochloric acid
and ethylene; and Döbereiner had regarded anhydrous oxalic acid as a
combination of carbonic acid with carbonic oxide.
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