History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Nevertheless, the significance of the generalisation discovered by
Dulong and Petit, in spite of its limitations, was quickly appreciated,
as it was perceived that a knowledge of the specific heat of an element
might be of great value in determining its atomic weight. The immediate
effect was that a certain number of the atomic weights fixed by
Berzelius mainly on chemical considerations were required to be halved.
Although subsequent experience has proved that the law of Dulong and
Petit is not capable of the simple mathematical expression they gave
it, it has shown itself to be of great value in fixing doubtful atomic
weights.
=Pierre Louis Dulong= was born in 1785 at Rouen, and, after studying
chemistry and physics at the Polytechnic School at Paris, became its
Professor of Chemistry and subsequently its Professor of Physics.
In 1830 he was made its Director of Studies; and in 1832 he became
permanent Secretary of the Academy of Sciences. As a young man he
worked with Berzelius, with whom he made the first approximately
accurate determination of the gravimetric composition of water. In
1811 he discovered the highly explosive _nitrogen chloride_, in the
investigation of which he was severely injured, losing an eye and
several fingers. He died in 1838. His collaborator, =Alexis Therese
Petit=, was born in 1791 at Vesoul, and died, when holding the position
of Professor of Physics at the Lycée Bonaparte, in 1820.
The attempt made by Neumann to extend Dulong and Petit’s “law” to
compound substances was only partially successful. Nor has any
important generalisation followed from our knowledge of the specific
heat of liquids. Almost simultaneously with the publication of Dulong
and Petit’s “law,” Mitscherlich made known the fact that similarity
in chemical constitution is frequently accompanied by identity of
crystalline form. Boyle, as far back as the middle of the seventeenth
century, had insisted upon the importance of the forms of crystals
in throwing light upon the internal structure of bodies. Romé de
l’Isle and Hauy had remarked that many different substances had the
same crystalline form. It had been observed that a crystal of potash
alum would continue to grow and preserve its shape in a solution of
ammonia alum; and similar observations had been shown to occur in
the case of vitriols. The invention of the reflecting goniometer by
Wollaston greatly facilitated the investigation of such phenomena.
Mitscherlich showed that the phosphates and arseniates of analogous
composition had the same crystalline shape, or, in other words, were
isomorphous. The same fact was observed to occur in the case of the
analogously constituted sulphates and selenates, and in that of the
oxides of magnesium and zinc, etc. The value of isomorphous relations
in determining the group-relationships of the elements and in deducing
the composition of salts was at once recognised by Berzelius, who
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