History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
styled the discovery of isomorphism by his pupil Mitscherlich as “the
most important since the establishment of the doctrine of chemical
proportions.” The quantities of the isomorphously replacing elements in
a compound were regarded by him as a measure of their atomic weights;
and the principle was subsequently constantly employed by him, whenever
possible, as a criterion in fixing their values. Other investigators
have followed his example in this respect; and isomorphism is still
regarded as an important consideration in establishing the genetic
relations of an element.
=Eilhard Mitscherlich=, the son of a minister, was born in 1794 at
Neu Ende, near Jever, in Oldenburg, and, after studying philology
and oriental languages at Heidelberg, went to Paris, and thence to
Göttingen, where he occupied himself with natural science. In 1818
he repaired to Berlin and commenced to work on the arseniates and
phosphates, the similarity in the crystal-forms of which he was the
first to detect. His friend Gustav Rose, the mineralogist, thereupon
instructed him in the methods of crystallography; to enable him to
verify his discovery and to establish it by goniometric measurements.
In 1821 he joined Berzelius at Stockholm, where he pursued his
inquiries on the connection between crystal-form and chemical
composition. It was at the suggestion of Berzelius that he adopted the
term “isomorphy” to express this connection—the mechanical consequence
of identity of atomic constitution. In the same year he was appointed
Klaproth’s successor in Berlin, where he died in 1863.
Mitscherlich also worked on the manganates and permanganates, on
selenic acid, on benzene and its derivatives, and on the artificial
production of minerals.
The study of the physical phenomena of gases, initiated in 1660
by Boyle’s discovery of the law of gaseous pressure, has greatly
contributed to our knowledge of their intrinsic nature. Boyle himself
only proved his law in the case of atmospheric air; but the observation
was subsequently (1676) generalised by Marriotte. Charles, Dalton,
and Gay Lussac independently showed that gases have the same rate of
thermal expansion.
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