History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Other experimenters, among whom may be mentioned Thilorier and
Natterer, greatly improved the mechanical appliances for liquefying
these gases; liquid carbonic acid and nitrous oxide were obtained
in considerable quantities, and employed in the production of cold.
Certain of the gases—hydrogen, oxygen, nitrogen, nitric oxide, carbonic
oxide, etc.—resisted all attempts to liquefy them; and hence gaseous
substances came to be classified as _permanent_ and _non-permanent_,
depending upon whether they could or could not be liquefied. The
division was felt to be irrational even at the time it was made. There
seemed no _à priori_ reason why carbon dioxide and nitrous oxide should
be liquefiable, while carbonic oxide and nitric oxide should resist
all attempts to coerce them into changing their state. The real clue
to the conditions required to effect the liquefaction of a gas was
not discovered until nearly half a century later, when, as will be
shown subsequently, the arbitrary division of gases into permanent and
non-permanent was swept away.
The discovery of the law of gaseous combination by Gay Lussac, and the
recognition by Ampère and Avogadro of the relation between the density
of a gas or a vapour and its atomic weight, early led to improvements
in the methods of determining the absolute weights of gases and
vapours, especially by French chemists. Both Gay Lussac and Dumas
devised processes for determining vapour densities which were in use
until late in the century, and which, although now superseded by more
convenient and more rapid modifications afforded valuable information
concerning the molecular weights of substances and the phenomena of
gaseous dissociation.
During the first decade of the nineteenth century Dalton and Henry
discovered the simple law which connects pressure with the solubility
of a gas in any solvent upon which it exerts no specific action. Dalton
further developed the law so as to include the absorption by a solvent
of the several constituents of a gaseous mixture.
Attempts were made by Schröder, Kopp, and others, to discover
relations between the weights of unit volumes of liquids and solids
and their chemical nature; but such attempts were only partially
successful, owing to the difficulty of finding valid conditions
of comparison. By comparing the specific gravities of liquids
at their boiling-points Kopp succeeded in detecting a number of
regularities among their specific volumes which seem to indicate that
a comprehensive generalisation connecting them may yet be discovered.
Kopp has also shown that regularities exist among the boiling-points
of correlated substances, and that there is an interdependence between
the temperature of their ebullition and the chemical characters of
compounds.
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