History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
That gases are made up of particles possessing an internal movement was
surmised by the Greeks; but experimental evidence for such a view of
their constitution was first presented by Thomas Graham in 1829–1831,
when he discovered that gases move, or are diffused, at rates inversely
proportional to the square roots of their densities. Observations of a
like character, which found their explanation in Graham’s discovery,
had previously been made by Priestley, Döbereiner, and Saussure. This
interchange in the position of their particles is a property inherent
in gases. Inequality of density is not essential to diffusion. Graham
proved this by connecting together two vessels, one containing nitrogen
and the other carbonic oxide, which have the same density. After the
expiration of a certain time both gases were found to be uniformly
diffused through the vessels.
How these laws were found to be interdependent and mutually connected,
and how they led up to a molecular theory of gases which serves
to explain them, as well as certain other gaseous phenomena to be
subsequently noted, will be shown in the second part of this work.
By the end of the period with which we are concerned—that is, the
middle of the nineteenth century—a considerable body of information had
been accumulated as to the conditions which determine the different
states of aggregation of matter—that is, the conditions which allow of
the passage of the gaseous state into that of the liquid, and of the
liquid into that of the solid. That the same substance was capable of
existence in the three states of gas, liquid, and solid was of course
evident from the case of water. Even the most primitive races must
have realised that steam, dew, rain, snow, hail, and ice were only
modifications of one and the same substance. As knowledge increased,
other substances came to be known which resembled water in their
capacity for existence in various physical states. It was but natural
to assume that this was a general attribute, and that all substances
would, sooner or later, be found capable of existence in each of the
different conditions of aggregation.
Attempts were made during the first quarter of the last century to
prove that all the æriform bodies then known were simply vapours
more or less remote from their point of liquefaction, and still
further removed from their point of congelation. Monge and Clouet
condensed sulphur dioxide some time before 1800; and Northmore,
in 1805, liquefied chlorine. But these observations attracted
little attention until Faraday, in 1823, independently effected the
liquefaction of chlorine, and Davy that of hydrochloric acid. Faraday
almost immediately afterwards liquefied sulphur dioxide, sulphuretted
hydrogen, carbon dioxide, euchlorine, nitrous oxide, cyanogen, and
ammonia.
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