History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
│Thomas Graham│ was born in Glasgow on December 21, 1805, and, after
studying under Thomas Thomson at the University of that city, attended
the lectures of Hope and Leslie in Edinburgh. In 1830 he succeeded Ure
as teacher of chemistry at Anderson’s College in Glasgow, and in 1837
was called to the Chair of Chemistry in the newly-founded University of
London, in succession to Edward Turner. In 1854 he was made Master of
the Mint. He died in London on September 16, 1869.
Graham’s work was mainly devoted to that section of the science now
known as physical chemistry. His contributions to pure chemistry
are few in number. By far the most important is his discovery of
_metaphosphoric_ acid and its relations to the other modifications of
phosphoric acid. Ortho- or ordinary phosphoric acid was known to
Boyle; pyrophosphoric acid was discovered by Clark. Graham’s work is
noteworthy as first definitely indicating the inherent property of the
acids to combine with variable but definite amounts of basic substances
by successive replacement of hydroxyl groups—the property we now term
_basicity_, and was of fundamental importance in regard to its bearing
on the constitution of acids and salts.
Graham’s fame chiefly rests upon his discovery of _the law of gaseous
diffusion_ (1829–1831), upon his work on the _diffusion of liquids_,
and upon his recognition of the condensed form of hydrogen he termed
_hydrogenium_. Questions involving the conception of molecular
mobility, indeed, constituted the main feature of his inquiries. We owe
to him, among others, the terms _crystalloid_, _colloid_, _dialysis_,
_atmolysis_, _occlusion_—all of which have taken a permanent place in
the terminology of science.
[Illustration: ALEXANDER WILLIAM WILLIAMSON.]
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