History of Chemistry, Volume 2 (of 2): From 1850 to 1910 — John Shaqi
History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
What was long known as _didymium_ (διδυμος = a twin) was discovered by
Mosander in 1841. It owes its name to its close chemical relationship
to, and almost constant association with, _lanthanum_—both elements
occurring in many minerals, more particularly in _cerite_, _allanite_,
and _monazite_. In 1885 Auer von Welsbach announced that the didymium
of Mosander was, in reality, a mixture of two elements which could be
separated by the systematic fractional crystallisation of the double
ammonium nitrates; to these elements he gave the names _praseodymium_
(πράσινος, leek-green) and _neodymium_ (νέος, new). Neodymium salts
are rose-coloured, whereas those of praseodymium are green, and the
elements are further characterised by differences in their absorption
and spark-spectra. When mixed, the substances give the spectrum
originally considered to be characteristic of didymium.
_Samarium_ was discovered in 1879 by Lecoq de Boisbaudran in
_samarskite_. Its salts are yellow, and afford in solution
characteristic absorption bands.
It is not improbable that many of the minerals from which the so-called
rare earths are obtained contain elements hitherto unrecognised, and it
is possible that certain of the substances now assumed to be elements
may, like didymium, turn out to be mixtures. In fact, additional
elements have from time to time been announced, as for example, the
_decipium_ of Delafontaine (1878) and the _monium_ or _victorium_ of
Crookes (1899), pronounced by Urbain to be identical with gadolinium:
their individuality cannot as yet be said to be established. Didymium
itself was stated by Krüss and Nilson (1888) to be even more
complicated than the work of Auer von Welsbach would seem to indicate,
and to contain no fewer than eight elementary substances. As yet,
however, no confirmation of this surmise has been obtained.
The chemistry of the rare earths has of late years been greatly
extended owing to the employment of certain of the members of the
group in the manufacture of the “mantles” used in gas-lighting, and
which consist substantially of thoria, mixed with about one per cent.
of ceria. Large quantities of _monazite_, _thorianite_, _thorite_,
_cerite_, and other minerals, are now worked up for the sake of the
thoria and ceria they contain, and considerable amounts of residual
products, consisting largely of other members of the family, are now
available for investigation. It is reasonably certain, therefore, that
our knowledge of this section of inorganic chemistry will be largely
augmented in the immediate future. Indeed, the application of thoria
to the construction of gas-mantles may be said to have removed that
substance from the category of the rare elements. No sooner was it
discovered that it was capable of useful application than unexpected
sources of supply were found.
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