History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Julius Thomsen, of Copenhagen, in a paper published in 1895, entitled
_On the Probability of the Existence of a Group of Inactive Elements_,
pointed out, in relation to Mendeléeff’s Law of Periodicity (see
_ante_), that in periodic functions the change from negative to
positive value, or the reverse, can take place only by a passage
through zero or through infinity; in the first case the change
is gradual, and in the second case it is sudden. The first case
corresponds with the gradual change in electrical character with rising
atomic weight in the separate series of the periodic system, and the
second case corresponds with a passage from one series to the next.
It therefore appears that the passage from one series to the next in
the periodic system should take place through an element which is
electrically indifferent. The valency of such an element would be zero,
and therefore in this respect also it would represent a transitional
stage in the passage from the univalent electronegative elements of the
seventh to the univalent electropositive elements of the first group.
This indicates the possible existence of a group of inactive elements
with the atomic weights 4, 20, 36, 84, 132—numbers corresponding fairly
closely with the atomic weights respectively of helium, neon, argon,
krypton, and xenon.
* * * * *
No discovery of recent years has created more widespread interest than
that of the radio-active elements.
In 1896 Henri Becquerel found that uranium salts emitted an invisible
radiation which had the power of affecting a photographic plate,
even though not directly exposed to it, exactly in the same way as
the Röntgen or X-rays. Since that time a number of substances have
been shown to possess a similar property. Such substances are said
to be radio-active. The radiation emitted by them is not uniform in
character. It has been found to be of three distinct types, known
respectively as the α, β, and γ radiations. The α rays consist of
positively electrified particles moving with a velocity equal to about
a fifteenth of that of light. These rays have little penetrative power,
and are capable of being deflected by a magnet.
The β rays consist of negatively electrified particles of a mass not
greater than one thousandth of that of the hydrogen atom, and they
move with a velocity approximating to that of light. The β rays have a
greater penetrative power than the α rays, and are even more readily
deflected by a magnet.
The γ rays are analogous to, if not identical with, the X or Röntgen
rays; they move with the velocity of light, have a high penetrative
power, but are not affected by the magnet. All three forms of
radiation render gases electrically conductive, excite luminescence or
fluorescence in certain substances, change the colour of glass, convert
oxygen into ozone and yellow phosphorus into red phosphorus, and act
upon photographic plates.
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