History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Nevertheless, the occurrence of such numerical relationships continued,
as already stated, to excite speculation. Döbereiner, in 1829, pointed
out that in certain groups of correlated elements, consisting each
of three members, the middle member had an atomic weight practically
identical with the arithmetic mean of the atomic weights of the others;
and similar observations were made by Gmelin, Dumas, Gladstone, and
Strecker. An approach to the recognition of the general law underlying
these facts was made by Newlands in England, and independently by
De Chancourtois in France, who were the first to indicate that the
properties of the elements are related to their atomic weights. This
conception was developed by the Russian chemist, Mendeléeff. In
Mendeléeff’s arrangement, first published in 1869, the elements are so
grouped that their properties are periodic functions of their atomic
weights. The general statement of what is now known as the Periodic
Law may be put in this form: If the elements are arranged in order
of increasing atomic weight, the properties of these elements vary
from member to member of the series, but return more or less nearly
to the same value at certain fixed points in the series. This is
observed to occur in the atomic value, or valency, of the several
members; also in their specific volumes, melting-points, ductility,
hardness, volatility, crystalline form, thermal expansion, refraction
equivalents, and conductivities for heat and electricity, in their
magnetic properties and electro-chemical behaviour, and in their heats
of chemical combination, etc.
The first chemist of note to grasp the significance of Mendeléeff’s
generalisation was Lothar Meyer, who, dealing at the outset with one of
the characteristic properties of the elements—viz., their specific or
atomic volumes (that is, the values obtained by dividing their specific
gravities into their respective atomic weights)—greatly developed
the principle of periodicity, representing it graphically in a most
striking and suggestive manner, leading up to a classification almost
identical with that of Mendeléeff.
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