History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Since the date of its promulgation the scheme of classification
of the elements in accordance with the principle of periodicity
has experienced certain minor modifications necessitated by fuller
knowledge; but in its essential features it remains very much in the
form devised by Mendeléeff. The discovery of the so-called inert and
radio-active elements required that their relations to the periodic law
should be defined. Their inclusion raises no fundamental difficulty.
Indeed, the generalisation seems to adapt itself to the far-reaching
considerations which spring from modern views of the nature of the
atom, its electro-chemical relationships, and the orderly arrangement
of the corpuscles of which it may be composed. In the 1905 edition
of the English translation of his famous _Principles of Chemistry_,
Mendeléeff has given a table which may be said to embody his final
views concerning the systematic classification of the elements. This
is reproduced on p. 105. In this table he postulates the existence of
two hypothetical elements, _x_ and _y_, the former of which he regards
as identical with the physical ether; while the latter is an analogue
of helium, possibly identical with the “coronium” of the solar coronal
atmosphere, with a molecular weight of about 0.4.
The striking feature of Mendeléeff’s generalisation is its
universality. In this respect it differs from all previous attempts
at natural classifications of the elements; these were limited and
partial, and therefore unsatisfactory. Nevertheless, it is easy to
trace in them fundamental conceptions upon which Mendeléeff built.
Mendeléeff, in fact, gave a great extension to ideas with which the
chemical world of half a century ago was more or less familiar; and
doubtless it was this circumstance, combined with the remarkable
boldness and comprehensiveness of this extension, followed almost
immediately by a most striking series of confirmations of his own
previsions, as logical consequences of his generalisation, that
secured for it attention, and ultimately universal adoption.
Public-domain text, read in full here on John Shaqi.
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