Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
“That the quantity of hydrogen evolved during the decomposition
of muriatic acid gas by metals, is the same that would be
produced during the decomposition of water by the same bodies,
appears, at first view, an evidence in favour of the existence
of water in muriatic acid gas; but as there is only one known
combination of hydrogen with oxymuriatic acid, one quantity must
always be separated. Hydrogen is disengaged from its oxymuriatic
combination by a metal, in the same manner as one metal is
disengaged by another from similar combinations.”
He once more shows that by the strongest analytical power he can
command oxymuriatic acid fails to yield any substance differing from
itself:
“I have caused strong explosions from an electrical jar, to pass
through oxymuriatic gas, by means of points of platina, for
several hours in succession; but it seemed not to undergo the
slightest change.”
Such, then, are the reasons which induced Davy to consider that
oxymuriatic acid contains no oxygen; that it had hitherto been
“undecompounded,” and that, therefore, by the strict logic of
chemistry, it was to be regarded as an elementary body. Had his paper
concluded at this point, his position would have been unassailable,
even in the light of nearly ninety years of subsequent work. But
he could not stop here. Berthollet, the author of the prevailing
theory, had discovered a salt then known as _hyper-oxymuriate_
of potash, presumably capable of furnishing an acid termed by
Chenevix _hyper-oxygenised muriatic acid_. This salt is now termed
potassium chlorate, after the acid which Davy subsequently succeeded
in isolating, and which, when the chlorine theory was generally
accepted, was called chloric acid by Gay Lussac. The existence of the
hyper-oxymuriate of potash was for a time a stumbling-block, and Davy
sought to explain it on the assumption that it was nothing more than a
triple compound of oxymuriatic acid, potassium, and oxygen.
“We have no right to assume the existence of any peculiar acid
in it, or of a considerable portion of combined water; and it is
perhaps more conformable to the analogy of chemistry to suppose
the large quantity of oxygen combined with the potassium, which
we know has an intense affinity for oxygen, and which from some
experiments, I am inclined to believe, is capable of combining
directly with more oxygen than exists in potash, than with the
oxymuriatic acid which, as far as is known, has no affinity for
that substance.”
Public-domain text, read in full here on John Shaqi.
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