Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
“Now as muriatic acid gas is known to consist of oxymuriatic
gas and hydrogen, there is no simple explanation of the result,
except by saying that the hydrogen of the muriatic acid combined
with oxygen from the peroxide to produce water.”
The bleaching power of chlorine had been explained by Scheele on the
supposition that it destroyed colours by combining with phlogiston.
Berthollet considered it to act by supplying oxygen. Davy then made
the well-known experiment proving that the dry gas “is incapable of
altering vegetable colours, and that its operation in bleaching depends
entirely upon its property of decomposing water and liberating its
oxygen.” It had been supposed that oxymuriatic acid gas was capable of
being condensed and crystallised at a low temperature. He shows that
it was only damp chlorine or its solution in water that yielded any
solid product. He exposed the pure gas, dried by muriate of lime, to a
temperature of -40° F., without observing any change. It is curious,
however, that liquid chlorine had actually been obtained by Northmore
five years before by heating the so-called hydrate of chlorine under
pressure. The phenomenon was misunderstood, and it was reserved for
Faraday, in 1823, to show that the product was actually the liquefied
gas.
Davy, who was not always happy in his suggestions as to chemical
nomenclature, proposed to denote the compounds of oxymuriatic gas by
the names of their bases with the termination _ane_.
“Thus, argentane may signify horn-silver; stannane Libavius’s
liquor; antimonane, butter of antimony; sulphurane, Dr. Thomson’s
sulphuretted liquor, and so on for the rest.... In cases when
two or more proportions of inflammable matter combine with one
of gas; or two or more of gas with one of inflammable matter, it
may be convenient to signify the proportions by affixing vowels
before the name, when the inflammable matter predominates, and
after the name when the gas is in excess; and in the order of the
alphabet, _a_ signifying two, _e_, three, _i_, four and so on.”
Thus he called phosphorus pentachloride _phosphorana_, and the
trichloride _phosphorane_, because there was a larger percentage
proportion of phosphorus in the latter compound than in the former.
That Davy was not unaware of the difficulties and inconveniences of
such a system of nomenclature may be inferred from what he says in his
“Elements” concerning the names for the two chlorides of mercury, the
true composition of which he was the first to discover:--
“The names _mercurane_ and _mercurana_ which may be adopted to
signify the relations of their composition, are too similar to
each other to be safely used as familiar appellations for the two
substances, as corrosive sublimate is a powerful poison, calomel
an excellent medicine.”
Public-domain text, read in full here on John Shaqi.
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