Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
“As the new compound in its purest form is possessed of a
bright yellow-green colour, it may be expedient to designate it
by a name expressive of this circumstance and its relation to
oxymuriatic gas. As I have named that elastic fluid Chlorine; so
I venture to propose for this substance the name Euchlorine, or
Euchloric gas from ευ and χλωρος. The point of nomenclature I am
not inclined to dwell upon. I shall be content to adopt any name
that may be considered as most appropriate by the able chemical
philosophers attached to this Society” [the Royal Society].
Euchlorine was subsequently discovered by Soubeiran to be a mixture of
chlorine and chlorine peroxide, a gas which Davy himself afterwards
isolated in a pure state. It is however obvious from the accounts he
gives that even in his first paper he must have been experimenting
with a fairly pure product, due probably to the circumstance that he
had collected the mixed gases over mercury, which retains the greater
part of the chlorine. Former experimenters had collected the gas over
water, which dissolves the chlorine peroxide more readily than the
chlorine. Madame de Staël once observed that an interesting book might
be written on the important consequences which have sprung from little
differences. It ought to be noted, however, that Davy had himself
doubts whether his euchlorine was not a mixture of chlorine and the gas
which he subsequently discovered, and to which he says: “I shall not
propose to give any name till it is determined whether euchlorine is a
mixture or a definite compound.”
It has been stated that Davy discovered the two chlorides of
phosphorus. In a paper read to the Royal Society on June 18th, 1812,
“On some Combinations of Phosphorus and Sulphur and on some other
Subjects of Chemical Inquiry,” he reverts to these substances, as
they “offer decided evidences in favour of an idea that has been for
some time prevalent among many enlightened chemists and which I have
defended in former papers published in the Philosophical Transactions;
namely that bodies unite in definite proportions, and that there is a
relation between the quantities in which the same element unites with
different elements.”
He first makes a determination, singularly accurate for the time, of
the amount of chlorine contained in the lower chloride, and finds
that 13·6 grains on decomposition with water afforded 43 grains of
horn-silver; theory requires 42·6 grains. By synthetical experiments
he came to the conclusion that the amount of chlorine absorbed by
phosphorus to form the higher chloride was exactly double that
contained in the lower chloride: he found that 3 grains of phosphorus
combined with 20 grains of chlorine: in reality it should require only
17¾ grains.
Public-domain text, read in full here on John Shaqi.
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