Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
After reciting the above facts he explains why he has ventured to take
up a subject on which Gay Lussac was still engaged. The explanation
was no doubt necessary; he had evidently not forgotten Gay Lussac’s
intrusion into his own field of work on the occasion of the discovery
of the metals of the alkalis. He first draws attention to the
peculiarities of the combination of the new substance with silver;
this, he shows, is markedly different from silver chloride. He then
forms this compound synthetically; forms also the combination with
potassium by direct union, and describes its properties; studies the
action of chlorine on the new substance, and notes the formation of
the yellow solid chloride and the mode of its decomposition by water;
prepares a number of metallic compounds; studies the action of the
new substance on phosphorus, the nature of the product, and its mode
of decomposition by water, with formation of the white crystalline
phosphonium iodide and hydriodic acid gas. By acting on this gas with
potassium he shows that it yields half its volume of hydrogen and forms
the same product as by the direct union of the alkali metal with the
new substance. He further finds that this gas is formed when the new
substance and hydrogen are passed through a heated tube; it has a very
strong attraction for water, which dissolves it to a large extent, and
the concentrated solution rapidly becomes tawny. When the new substance
is treated with potash solution it forms the same product as by its
direct union with potassium, together with a salt precisely similar to
potassium hyper-oxymuriate, and which, like that salt, is decomposed
when heated, with evolution of oxygen. He shows that the new substance
is expelled from its compounds when these are heated with chlorine.
He studies the nature of the black fulminating compound discovered
by Desormes and Clement by acting on the new substance with solution
of ammonia, and concludes that it is analogous to the detonating oil
of Dulong. He attempts to determine the combining proportion of the
new substance, on the assumption that its compounds are analogous to
those of chlorine, but he has to admit that his experiments have been
made upon quantities too small to afford exact results. Nevertheless
they prove that the value is much higher than those of the simple
inflammable bodies, and higher even than those of most of the metals.
He further shows that the combination with hydrogen must be one of the
heaviest elastic fluids existing.
Public-domain text, read in full here on John Shaqi.
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