Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
“The author [Davy] derived no assistance whatever from the
Count’s ingenious labours. My first knowledge of him arose from
a letter written in April 1798, containing an account of his
researches on heat and light; and his first knowledge of Count
Rumford’s paper was conveyed by my answer. The two Essays contain
proofs enough of an original mind to make it credible that
the simple and decisive experiments on heat were independently
conceived. Nor is it necessary, in excuse or in praise of his
system, to add, that, at the time it was formed, the author was
under twenty years of age, pupil to a surgeon-apothecary, in the
most remote town of Cornwall, with little access to philosophical
books, and none at all to philosophical men.”
Having thus, with Beddoes, expunged caloric from his chemical system,
Davy proceeds to elevate the matter of light into its place. According
to Lavoisier oxygen gas was a compound of a simple substance and
caloric; Davy seeks to show that it is a compound of a simple substance
and light. He objects to the use of the word “gas,” since, according to
French doctrine, it is to be taken as implying not merely a state of
aggregation but a combination of caloric with another substance, and
suggests therefore that what was called oxygen gas should henceforth be
known as _phosoxygen_. His “proofs” that oxygen is really a compound of
a simple substance with “matter in a peculiar state of existence” are
perhaps the most futile that could be imagined. Charcoal, phosphorus,
sulphur, hydrogen, and zinc were caused to burn in oxygen; _light_ was
evolved, oxides were formed, _and a deficiency of weight was in each
case observed_. He regrets, however, that he “possessed no balance
sufficiently accurate to determine exactly the deficiency of weight
from the light liberated in different combustive processes.”
“From these experiments, it appears that in the chemical process
of the formation of many oxyds and acids, light is liberated,
the phosoxygen and combustible base consumed, and a new body
formed.... Since light is liberated in these processes, it is
evident that it must be liberated either from the phosoxygen
or from the combustible body.... If the light liberated in
combustion be supposed (according to Macquer’s and Hutton’s
theories) to arise from the combustible body, then phosoxygen
must be considered as a simple substance; and it follows on this
supposition, that whenever phosoxygen combines with combustible
bodies, either directly or by attraction from any of its
combinations, light must be liberated, which is not the case, as
carbon, iron and many other substances, may be oxydated by the
decomposition of water without the liberation of light.”
Public-domain text, read in full here on John Shaqi.
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