Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
The singular property possessed by ammonium nitrate of decomposing
in several distinct modes according to the rapidity of heating and
the temperature to which the substance is raised, first indicated by
Davy, has been minutely studied by M. Berthelot, who has shown that
this comparatively simple salt may be decomposed in as many as six
different ways. It may be (1) dissociated into gaseous nitric acid and
ammonia; (2) decomposed into nitrous oxide and water; (3) resolved into
nitrogen, oxygen, and water, (4) or into nitric oxide, nitrogen, and
water, (5) or into nitrogen, nitrogen peroxide, and water; or lastly
(6), under the influence of spongy platinum, it may be resolved into
gaseous nitric acid, nitrogen, and aqueous vapour. These different
modes of decomposition may be distinct or simultaneous; or, more
exactly, the predominance of any one of them depends on relative
rapidity and on the temperature at which decomposition is produced.
This temperature is not fixed, but is itself subordinate to the
rapidity of heating (_cf._ Berthelot’s “Explosives and Their Power,”
translated by Hake and Macnab). The assertion of De la Metherie, that
the gas produced by the solution of platinum in nitromuriatic acid was
identical with the dephlogisticated nitrous air of Priestley (nitrous
oxide), led Davy to examine the gaseous products of this reaction more
particularly. He had no difficulty in disproving the statement of the
French chemist; but his observations, although accurate, led him to
no definite conclusion. “It remains doubtful,” he says, “whether the
gas consists simply of highly oxigenated muriatic acid and nitrogen,
produced by the decomposition of nitric acid from the coalescing
affinities of platina and muriatic acid for oxygen; or whether it is
composed of a _peculiar_ gas, analogous to oxigenated muriatic acid and
nitrogen, generated from some unknown affinities.” The real nature of
the gas, which has also been considered by Lavoisier as a particular
species, not hitherto described, was first established by Gay Lussac,
when Davy had himself proved that “oxigenated muriatic acid” was a
simple substance.
In the second section the combinations and composition of nitrous
oxide are investigated, and an account is given of its decomposition
by combustible bodies, and a series of experiments are described which
are now among the stock illustrations of the chemical lecture-room.
As to its composition, he says, “taking the mean estimations from the
most accurate experiments, we may conclude that 100 grains of the known
ponderable matter of nitrous oxide consist of about 36·7 oxygen and
63·3 nitrogen”--no very great disparity from modern numbers, viz. 36·4
oxygen and 63·6 nitrogen. He concludes this section with a short review
of the characteristic properties of the combinations of oxygen and
nitrogen, among which he is led to class atmospheric air.
Public-domain text, read in full here on John Shaqi.
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