Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
In the second section, “On the Agencies of Electricity in the
Decomposition of various Compounds,” he begins by pointing out that in
all the experiments recorded in the preceding section--that is, in all
changes in which acid and alkaline matter had been present--the acid
matter collected in the water round the positive pole, and the alkaline
matter round the negative pole. This he shows to be true even of such
sparingly soluble substances as gypsum, the sulphates of strontium and
barium, and fluorspar. By connecting together cups or vessels made of
the substances under investigation by a thread of well-washed asbestos,
as suggested by Wollaston, he found that in all cases the acid element
collected round the positive, and the earthy base round the negative
pole. Basalt from Antrim, a zeolite from the Giant’s Causeway, vitreous
lava from Etna, and even glass, in like manner yielded alkaline matter
to water when subjected to the action of voltaic electricity. Soluble
salts, such as the sulphates of sodium, potassium, and ammonium, the
nitrates of potassium and barium, the succinate, oxalate and benzoate
of ammonium, were similarly decomposed: the acids in a certain time
collected in the tube containing the positive wire, and the alkalis and
earths in that containing the negative wire. When metallic solutions,
such as those of iron, zinc, and tin were employed, metallic crystals
or depositions were formed on the negative wire, and oxide was likewise
deposited round it; and a great excess of acid was soon found in the
opposite cup.
In the next section, “On the Transfer of Certain of the Constituent
Parts of Bodies by the Action of Electricity,” he points out that
the observations of Gautherot and of Hisinger and Berzelius rendered
it probable that the saline elements evolved in decompositions by
electricity were capable of being transferred from one electrified
surface to another, according to their usual order of arrangement, but
that exact observations on this point were wanting. He connected a cup
of gypsum with one of agate by means of asbestos, and filling each
with purified water, he inserted the negative wire of the battery in
the agate cup, and the positive wire in that of the sulphate of lime.
In about four hours he found a strong solution of lime in the agate
cup, and sulphuric acid in that of gypsum. By reversing the order, and
carrying on the process for a similar length of time, the sulphuric
acid appeared in the agate cup, and the solution of lime on the
opposite side. Many trials were made with other saline substances with
analogous results.
The time required for these transmissions (the quantity and intensity
of the electricity, and other circumstances remaining the same) seemed
to be related to the length of the intermediate column of water.
Public-domain text, read in full here on John Shaqi.
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