Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
To ascertain whether the contact of the saline solution with a
metallic surface was necessary for the decomposition and transference,
he introduced purified water into two glass tubes; a vessel containing
solution of potassium chloride was connected with each of the tubes by
means of asbestos; on introducing the wires into the tubes alkaline
matter soon appeared in one tube, and acid matter in the other; and in
the course of a few hours moderately strong solutions of potash and of
hydrochloric acid were formed.
Two tubes, one containing distilled water, the other a solution of
potassium sulphate, were each connected by asbestos threads with a
vessel containing a dilute solution of litmus; the saline matter was
negatively electrified; and as it was natural to suppose that the
sulphuric acid in passing through the water to the positive side would
redden the litmus in its course, some slips of litmus paper were placed
above and below the pieces of asbestos, directly in the circuit: it
was found that the acid and alkali passed through the litmus solution
without effecting any change in colour.
“As acid and alkaline substances during the time of their
electrical transfer passed through water containing vegetable
colours without affecting them, or apparently combining with
them, it immediately became an object of inquiry whether they
would not likewise pass through chemical menstrua having stronger
attractions for them; and it seemed reasonable to suppose that
the same power which destroyed elective affinity in the vicinity
of the metallic points would likewise destroy it, or suspend its
operation, throughout the whole of the circuit.”
To test this supposition, solution of potassium sulphate was placed
in contact with the negative wire, and pure water in contact with the
positive wire and a weak solution of ammonia was made the middle link
of the conducting chain, so that no sulphuric acid could pass to
the positive pole in the distilled water without passing through the
solution of ammonia.
In less than five minutes it was found that acid was collecting round
the positive pole, and in half an hour the water was sour to the
taste, and gave a precipitate with barium nitrate. Hydrochloric acid
from common salt, and nitric acid from nitre were transmitted through
concentrated alkaline menstrua under similar circumstances. Strontia
and baryta readily passed, like the other alkaline substances, through
hydrochloric and nitric acids; and _vice versâ_ these acids passed
with facility through aqueous solution of baryta and strontia; but it
was impossible to pass sulphuric acid through baryta or strontia, or
to pass baryta and strontia through sulphuric acid, as precipitates of
insoluble barium and strontium sulphate were formed.
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