Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
In the simplest case of electrical action, the alkali which receives
electricity from the metal would necessarily, on being separated from
it, appear positive, whilst the acid under similar circumstances would
be negative; and these bodies, having respectively with regard to the
metals that which may be called a positive and a negative electrical
energy, in their repellent and attractive functions seem to be governed
by laws the same as the common laws of electrical attraction and
repulsion.
The seventh section treats of “The Relations between the Electrical
Energies of Bodies and their Chemical Affinities”:--
“As the chemical attraction between two bodies seems to be
destroyed by giving one of them an electrical state different
from that which it naturally possesses; that is, by bringing it
artificially into a state similar to the other, so it may be
increased by exalting its natural energy. Thus, whilst zinc, one
of the most oxidable of the metals, is incapable of combining
with oxygen when negatively electrified in the circuit, even by
a feeble power; silver, one of the least oxidable, easily unites
to it when positively electrified; and the same thing might
be said of other metals. Amongst the substances that combine
chemically, all those, the electrical energies of which are
well known, exhibit opposite states; thus copper and zinc, gold
and quicksilver, sulphur and the metals, the acid and alkaline
substances, afford opposite instances; and supposing perfect
freedom of motion in their particles or elementary matter,
they ought according to the principles laid down, to attract
each other in consequence of their electrical powers. In the
present state of our knowledge it would be useless to attempt
to speculate on the remote cause of the electrical energy,
or the reason why different bodies, after being brought into
contact should be found differently electrified; its relation to
chemical affinity is however, sufficiently evident. May it not be
identical with it, and an essential property of matter?”
How Davy sought to elaborate a theory of chemical affinity on these
facts will be sufficiently obvious from the following extracts:--
“Supposing two bodies, the particles of which are in different
electrical states, and those states sufficiently exalted to give
them an attractive force superior to the power of aggregation,
a combination would take place which would be more or less
intense according as the energies were more or less perfectly
balanced; and the change of properties would be correspondently
proportional.”
Public-domain text, read in full here on John Shaqi.
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