Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
In the next section, “On Some General Observations on these Phenomena,
and on the Mode of Decomposition and Transition,” he summarises the
foregoing results:--
“It will be a general expression of the facts that have been
detailed, relating to the changes and transitions by electricity,
in common philosophical language, to say that hydrogen, the
alkaline substances, the metals, and certain metallic oxides,
are attracted by negatively electrified metallic surfaces,
and repelled by positively electrified metallic surfaces; and
contrariwise, that oxygen and acid substances are attracted
by positively electrified metallic surfaces, and repelled by
negatively electrified metallic surfaces; and these attractive
and repulsive forces are sufficiently energetic to destroy or
suspend the usual operation of elective affinity.
“It is very natural to suppose, that the repellent and attractive
energies are communicated from one _particle to another particle_
of the same kind, so as to establish a conducting chain in the
fluid; and that the locomotion takes place in consequence;
and that this is really the case seems to be shown by many
facts. Thus, in all the instances in which I examined alkaline
solutions through which acids had been transmitted, I always
found acid in them whenever any acid matter remained at the
original source....
“In the cases of the separation of the constituents of water,
and of solutions of neutral salts forming the whole of the
chain, there may possibly be a succession of decompositions,
and recompositions throughout the fluid. And this idea is
strengthened by the experiments on the attempt to pass barytes
through sulphuric acid, and muriatic acid through solution of
sulphate of silver, in which as insoluble compounds are formed
and carried out of the sphere of the electrical action, the power
of transfer is destroyed.”
In the next section, “On the General Principles of the Chemical Changes
produced by Electricity,” he points out that it had been already
shown by Bennet that many bodies brought into contact and afterwards
separated exhibited _opposite_ states of electricity; and that this
observation had been confirmed and extended by Volta, who had supposed
that it also takes place with regard to metals and fluids. In his
paper in the _Philosophical Transactions_ of 1801, the first he
sent to the Royal Society, Davy had shown that when alternations of
single metallic plates and acid and alkaline solutions were employed
in the construction of voltaic combinations, the alkaline solutions
always received the electricity from the metal, and the acid always
transmitted it to the metal.
Public-domain text, read in full here on John Shaqi.
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