Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
The Bakerian lecture in which Davy announces the discovery of the
compound nature of the fixed alkalis opens with a reference to the
concluding remarks of his lecture of the previous year, “that the new
methods of investigation promised to lead to a more intimate knowledge
than had hitherto been obtained concerning the true elements of bodies.
This conjecture, then sanctioned only by strong analogies, I am now
happy to be able to support by some conclusive facts.”
In the first attempts he made to decompose the fixed alkalis he acted
upon concentrated aqueous solutions of potash and soda with the highest
electrical power he could then command at the Royal Institution--viz.
from voltaic batteries containing 24 plates of copper and zinc of 12
inches square, 100 plates of 6 inches, and 150 of 4 inches, charged
with solutions of alum and nitric acid; but although there was high
intensity of action nothing but hydrogen and oxygen was disengaged. He
next tried potash in igneous fusion, and here the results were more
encouraging: there were obvious and striking signs of decomposition:
combustible matter was produced accompanied with flame and a most
intense light. He had observed that although potash when dry is a
non-conductor, it readily conducts when it becomes damp by exposure
to air, and in this state “fuses and decomposes by strong electrical
powers.”
“A small piece of pure potash, which had been exposed for a few
seconds to the atmosphere, so as to give conducting power to the
surface was placed upon an insulated disc of platina, connected
with the negative side of the battery of the power of 250 of 6
and 4, in a state of intense activity;[G] and a platina wire
communicating with the positive side was brought in contact with
the upper surface of the alkali....
“Under these circumstances a vivid action was soon observed
to take place. The potash began to fuse at both its points
of electrization. There was a violent effervescence at the
upper surface; at the lower, or negative surface, there was
no liberation of elastic fluid; but small globules having a
high metallic lustre, and being precisely similar in visible
characters to quicksilver appeared, some of which burnt with
explosion and bright flame, as soon as they were formed, and
others remained, and were merely tarnished, and finally covered
by a white film which formed on their surfaces.”
[G] It is frequently stated that Davy was enabled to isolate
the metals of the alkalis because of the _large_ and
powerful voltaic battery which he had at his disposal in
the Royal Institution. This is not correct. The battery he
employed was of very moderate dimensions, and not by any
means extraordinary in power. It was the success he thus
achieved that caused the large battery, which is probably
referred to, to be constructed, by special subscription, in
1809.
Public-domain text, read in full here on John Shaqi.
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