Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
The platina, as such, was, he found, in no way connected with the
result: a substance of the same kind was produced when copper, silver,
gold, plumbago, or even charcoal was employed for completing the
circuit.
“Soda when acted upon in the same manner as potash, exhibited
an analogous result; but the decomposition demanded greater
intensity of action in the batteries, or the alkali was required
to be in much thinner and smaller pieces.”
“The substance produced from potash remained fluid at the
temperature of the atmosphere at the time of its production; that
from soda, which was fluid in the degree of heat of the alkali
during its formation, became solid on cooling, and appeared
having the lustre of silver.”
It would seem from his description of its properties that the potassium
he obtained was most probably alloyed with sodium derived from impure
potash. Potassium is solid up to 143° F.; but, as Davy subsequently
found, an alloy of potassium and sodium is fluid at ordinary
temperatures.
When the potassium was exposed to air its metallic lustre was
immediately destroyed, and it was ultimately wholly reconverted into
potash by absorption of oxygen and moisture.
With the substance from soda the appearance and effects were analogous.
When heated in oxygen to a sufficiently high temperature, both
substances burnt with a brilliant white flame.
On account of their alterability on exposure to air, Davy had
considerable difficulty in preserving and confining them so as to
examine the properties of the new substances. As he says, like the
_alkahests_ imagined by the alchemists, they acted more or less upon
almost every body to which they were exposed.
He eventually found that they might be preserved in naphtha.
The “basis” of potash at 50° F. was a soft and malleable solid with the
lustre of polished silver.
“At about the freezing point of water it becomes harder and
brittle, and when broken in fragments, exhibits a crystallized
texture, which in the microscope seems composed of beautiful
facets of a perfect whiteness and high metallic splendour.”
It may be converted into vapour at a temperature approaching a
red-heat, and may be distilled unchanged; it is a perfect conductor
of electricity and an excellent conductor of heat. Its most marked
difference from the common run of metals was its extraordinarily low
specific gravity. Davy endeavoured to gain an approximation to its
relative weight by comparing the weight of a globule with that of an
equal-sized globule of mercury.
“Taking the mean of 4 experiments, conducted with great care,
its specific gravity at 62° Fahrenheit, is to that of mercury as
10 to 223, which gives a proportion to that of water nearly as 6
to 10; so that it is the lightest fluid body known. In its solid
form it is a little heavier.”
Public-domain text, read in full here on John Shaqi.
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