Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
The attempts made by Davy to decompose the alkaline earths by methods
similar to those adopted in the case of potash or soda were not
very successful, and it was only when he had received intimation
from Berzelius that they might be procured in the form of amalgams
by operating in contact with mercury that he obtained any decisive
results. In no case, however, was he able to prepare a pure metal,
and his description of the physical properties of the substances
he actually procured is exceedingly meagre. He seems to have been
satisfied for the moment in demonstrating that--
“The evidence for the composition of the alkaline earths is of
the same kind as that for the composition of the common metallic
oxides; and the principles of their decomposition are precisely
similar, the inflammable matters in all cases separating at the
negative surface in the voltaic circuit, and the oxygen at the
positive surface.”
“These new substances will demand names; and on the same
principles as I have named the bases of the fixed alkalies,
potassium and sodium, I shall venture to denominate the metals
from the alkaline earths barium, strontium, calcium and magnium;
the last of these words is undoubtedly objectionable but
magnesium has been already applied to metallic manganese [by
Bergman] and would consequently have been an equivocal term.”
However, as he states in his “Elements of Chemical Philosophy,” “the
candid criticisms of some philosophical friends” induced him to
subsequently change the name to magnesium.
He next made “Inquiries Relative to the Decomposition of Alumine,
Silex, Zircone, and Glucine,” but although he made a large number of
trials, the results were equivocal.
“Had I been so fortunate,” he says, “as to have obtained more
certain evidences on this subject, and to have procured the
metallic substances I was in search of, I should have proposed
for them the names of silicium, alumium, zirconium, and glucium.”
One of the most interesting sections of the paper relates to the
production of a so-called amalgam from ammonia, first obtained by
Berzelius and Pontin. This curious substance has been the subject of
much investigation, and little doubt is now entertained that it is
merely a mercurial froth, as first stated by Daniell--that is, mercury
distended by ammonia and hydrogen gases. Davy, however, saw in it the
proof of the presence of oxygen in ammonia, and of the existence of
what he called “the compound basis” of ammonia. He says:--
Public-domain text, read in full here on John Shaqi.
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