Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
“The more the properties of the amalgam obtained from ammonia
are considered the more extraordinary do they appear. Mercury by
combination with about 1/12000 part of its weight of new matter
is rendered a solid, yet has its specific gravity diminished
from 13·5 to 3, and it retains all its metallic characters;
its colour, lustre, opacity, and conducting powers remaining
unimpaired. It is scarcely possible to conceive that a substance
which forms with mercury so perfect an amalgam, should not be
metallic in its own nature; and on this idea to assist the
discussion concerning it, it may be conveniently termed ammonium.”
Davy’s term “ammonium” is still retained in chemical nomenclature, but
there is at present no evidence for the independent existence of such
an entity; the so-called ammonium amalgam is certainly no proof.
On December 15th, 1808, he delivered his third Bakerian lecture. It was
entitled “An Account of some new analytical Researches on the Nature
of certain Bodies, particularly the Alkalies, Phosphorus, Sulphur,
Carbonaceous Matter, and the Acids hitherto undecompounded, with some
general Observations on Chemical Theory.” Although this is one of
the longest and most laboured of Davy’s papers, it is, perhaps, one
of the least satisfactory. It is a record of many experiments with
few definite results. Few as these were, they yet paved the way for
consequences of the greatest importance. Gay Lussac and Thenard, on the
publication of Davy’s second Bakerian lecture, succeeded in devising a
method by which larger quantities of potassium might be obtained than
by the electrolytic process. It consisted in passing molten potash
over heated metallic iron and condensing the volatilised potassium in
naphtha. On heating potassium in ammonia, they found that hydrogen was
obtained together with potash, whence they concluded that potassium
was a _hydruret of potash_. This experiment was repeated by Davy; he
observed the formation of a substance since known as _potassamide_,
and completely disproved the conjecture of the French chemists. His
experiments on sulphur, phosphorus, and the various forms of carbon
were, however, wholly fallacious, and his conclusions as to the
non-elementary nature of these substances were erroneous, and were
subsequently corrected by him. His work on the decomposition of boracic
acid is, however, accurate, and he has every right to be considered as
an independent discoverer, with Thenard, of the element subsequently
called by him _boron_. At first Davy was inclined “to consider the
boracic basis as metallic in its nature,” and to propose for it the
name of _boracium_. His experiments with “fluoric acid” were vitiated
by the circumstance that he worked with a mixture of hydrofluoric
acid and silicon fluoride. Unwittingly he obtained small quantities
of silicon, although he failed to recognise the individuality of this
substance.
Public-domain text, read in full here on John Shaqi.
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