Humphry Davy, Poet and PhilosopherThorpe, T. E. (Thomas Edward)
Science
Humphry Davy, Poet and Philosopher
Thorpe, T. E. (Thomas Edward)
Davy, Humphry, Sir, 1778-1829
On November 16th, 1809, he read his fourth Bakerian lecture. It
was “On some new Electrochemical Researches on various Objects,
particularly the metallic Bodies, from the Alkalies and Earths, and on
some Combinations of Hydrogene.” He begins by again drawing attention
to the various surmises which had been made respecting the true nature
of potassium and sodium. Although these substances had been isolated,
and in the hands of chemists for upwards of two years, their properties
were so extraordinary when compared with those of the metals in
general, that many philosophers hesitated to consider them as true
metals. Gay Lussac and Thenard, as already mentioned, regarded them as
compounds of potash or soda with hydrogen; Curaudau as combinations of
carbon or carbon and hydrogen with the alkalis; whilst an ingenious
inquirer in this country communicated to Nicholson’s Journal his
belief that they were really composed of oxygen and hydrogen! Davy,
in the light of the fuller knowledge he obtained from Gay Lussac and
Thenard’s paper in the “Mem. d’Arcueil”--a copy of which he owed to
Berthollet--had no difficulty in again proving “that by the operation
of potassium upon ammonia, it is not a _metallic_ body that is
decompounded, but the volatile alkali, and that the hydrogen produced
does not arise from the potassium, as is asserted by the French
chemists, but from the _ammonia_.”
M. Curaudau’s hypothesis is shown to be based upon the accidental
association of naphtha with the metals he employed. In repeating some
experiments of Ritter’s, designed to show that potassium contained
hydrogen, Davy was led to the discovery of _telluretted hydrogen_, the
properties of which he describes in some detail. Tellurium at that time
was regarded as a metal, but Davy points out its strong analogies to
sulphur, with which element, indeed, it is now classed. Incidentally
he throws light upon the nature of the intolerably fetid product known
as “the fuming liquor of Cadet,” obtained by distilling acetate of
potash with arsenious oxide. On account of its extreme inflammability,
it was thought by Davy that this liquid might possibly be a pyrophorus
or volatile alloy of potassium and arsenic.
“From a repetition of the process I find that though potash is
decompounded in this operation yet that the volatile substance
is not an alloy of potassium but contains charcoal and arsenic
probably with hydrogen. The gases not absorbable by water given
off in this operation are peculiar. Their smell is intensely
fetid. They are inflammable, and seem to contain charcoal,
arsenic and hydrogen: whether they are mixtures of various gases,
or a single compound, I am not at present able to decide.”
So far as it goes, this description of the nature of the substance
is correct; it was Bunsen, in 1837, who first demonstrated the real
character of “the fuming liquor of Cadet.”
Public-domain text, read in full here on John Shaqi.
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