The hills of extreme southern Illinois contain several mineral materials that are entirely or largely restricted, in important quantities, to that part of the state. Some of them, such as silica and novaculite, come directly from bedrock deposits of great age; others, such as some of the sands and gravels, are of more recent origin. Silica (Tripoli) A mineral material unique in Illinois is the amorphous silica, or tripoli, mined in the hills of southern Illinois about 20 miles north of Cairo. Most of the silica mines are found at the heads of valleys or in tree-covered hill slopes along the less traveled roads. An arched opening (fig. 20) with a road leading into it may be all that is visible of the mine from the outside. Inside are many rooms, some 30 feet high, separated by rounded pillars about 20 feet thick that have been left to support the arched mine roof. Most of the silica in the mines is white, and this is the part that is mined. A silica deposit is made up of layers—some of white, powdery rock material, others that look chalky but are firm or hard. [Illustration: Figure 20—Entrance to a silica mine.] In the mines the silica is blasted loose from the natural deposit and loaded into trucks that take it to the processing mills at Elco and Tamms, where it is crushed and then transferred to huge grinding mills that pulverize it to a very fine powder. Air currents of different velocities separate the powder into various grades of fineness, and the finished silica goes into large paper bags for shipment. _Origin of Silica._—Some of the history of the formation of silica deposits is not fully known, but it seems probable that their original character was quite different from what it is today. Investigations by Survey geologists suggest that the parent rock formation was limestone and chert. The limestone was composed of the mineral calcite, but scattered through it were myriads of small particles of quartz. Interlayered with it were bands and beds of chert that contained varying amounts of calcite. As the rocks above them were worn away by the ceaseless erosion of streams and rivers, these original deposits were uncovered. Rain and snow-water then worked down into the limestone and chert deposits through cracks and crevices and dissolved the calcite in the rock. The quartz remained because it is much less soluble than the calcite. After many thousands of years all the calcite had been removed, leaving behind a “skeleton” of quartz—the silica deposits of today.