Risk is present in several branches of the ceramic industry. It is
greatest in glazing earthenware, but not infrequent also in the porcelain
and glass industries. It is impossible to deal with the extensive
literature on this subject exhaustively. A comprehensive and detailed
survey of lead poisoning in the ceramic industry on the Continent is
that by Kaup. Distinction is made between leadless glazes which melt
at high temperature and lead glazes which have the advantage of a low
melting-point. Galena and litharge are used in the preparation of glazes
for common earthenware and red and white lead for ware of better quality.
Distinction has to be made between a lead silicious glaze for pottery
ware, a lead and boric acid glaze for stoneware, and a lead and zinc
oxide glaze for ordinary faience and stoneware. Seegar, the celebrated
expert, praises the advantage of lead glaze and the use of lead in the
ceramic industry—it is indeed practically indispensable—and speaks of the
poisonous nature of lead as its only fault. The components of the glaze
must have definite relation to the hardness or softness of the body. The
higher the proportion of silicic acid in the glaze the harder the firing
it will stand; the more the flux materials are in excess the lower will
the melting point be.
The most important flux materials are, arranged in order of decreasing
fusibility, lead oxide, baryta, potash, soda, zinc oxide, chalk,
magnesia, and clay.
The _glaze_ is made by first mixing the ingredients dry, and then
either fritting them by fluxing in a reverberatory furnace and finally
grinding them very finely in water or using the raw material direct. In
the fritting process in the case of the lead glazes the soluble lead
compounds become converted into less soluble lead silicates and double
silicates.
The glaze is applied in different ways—dipping, pouring, dusting,
blowing, and volatilising. Air-dried and biscuited objects are dipped;
pouring the glaze on is practised in coarse ware, roofing-tiles, &c.;
dusting (with dry finely ground glaze, litharge, or red lead) also in
common ware; glaze-blowing (aerographing) and glaze dusting on porcelain.
In these processes machines can be used. Bricks are only occasionally
glazed with glazes of felspar, kaolin, and quartz, to which lead oxide
is often added in very large quantity. Lead poisoning in _brick works_
in view of the infrequent use of lead is not common, but when lead is
used cases are frequent. Kaup quotes several cases from the factory
inspectors’ reports: thus in three roof-tiling works examination by the
district physician showed that almost all the workers were affected.
_Coarse ware pottery_ is made of pervious non-transparent clay with
earthy fracture—only a portion of this class of ware (stoneware) is
made of raw materials which fire white. Such ware generally receives a
colourless glaze. The clay is shaped on the potter’s wheel, and is then
fired once or, in the better qualities, twice.
Public-domain text, read in full here on John Shaqi.
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