PREPARATION.—Mercury is obtained by roasting cinnabar (sulphide of
mercury). When cinnabar is heated with access of air the sulphide burns
to sulphur dioxide and the mercury volatilises and is subsequently
condensed. Formerly the process was carried on in open hearths; now it
is done usually in blast furnaces. The mercury is condensed in Idria
in large chambers cooled with water, while at Almaden in Spain it is
collected in a series of small earthenware receptacles (aludels), from
small openings in which the mercury flows in gutters and collects. The
mercury so recovered is usually redistilled.
On the walls of the condensers a deposit of sulphide and oxide of mercury
collects, removal of which is one of the operations most attended with
risk.
Recovery of silver or gold by amalgamation with mercury is carried on
only in America. The metallic silver or gold is taken up by the mercury,
from which it is recovered by distillation.
The conditions in the quicksilver mines of Idria in Austria have improved
of late years. Thus in the five years prior to 1886 of 500 cases of
illness more than 11 per cent. were due to chronic mercurial poisoning.
In 1906, 209 persons were employed, of whom only one-third were permanent
hands. Among these the sickness rate was very high (95-104 per cent.).
Of 741 cases of illness among the miners there were six of mercury
poisoning, and of 179 among persons employed in recovery of the metal,
twelve cases.[1]
The conditions of employment in the cinnabar mines of Monte Amiata in
Italy have recently been described in detail.[2] Here, although the
recovery of the metal is carried out in modern furnaces, thus greatly
reducing the danger, nevertheless nearly all the furnace workers suffer
from chronic poisoning.
In _silvering of mirrors_ the leaf of tinfoil was spread out on an
inclined table; mercury was poured over it and the sheet of glass laid
on the top with weights. The superfluous mercury was squeezed out and
ran away owing to the sloping position of the table. Now this process,
even in Fürth, is almost entirely replaced by the nitrate of silver and
ammonia process. Years ago the number of cases of poisoning was very
serious in places where, as in Fürth, the work was carried on as a home
industry.
In the production of _incandescent electric bulbs_ danger arises from
breaking of the glass pipes of the pumps and scattering of mercury on
the floor of the workrooms. Since there is a growing tendency to replace
mercury pumps by air pumps such cases ought to become rare.
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