In _water gilding_—a process little employed now—the metal objects
(military buttons, &c.) to be gilded, after treatment with a flux, are
brushed over with the mercury amalgam, and subsequently fired to drive
off the mercury. Unless careful provision is made to carry away the
vapour chronic poisoning cannot fail to occur. Even sweeps have been
affected after cleaning the chimneys of water gilders’ workshops. In
Great Britain, between 1899 and 1905, six cases were reported among water
gilders.
In the _manufacture of barometers_ and thermometers mercury poisoning is
not infrequent. Between 1899 and 1905 sixteen such cases were reported in
England; during the same period there were seventeen cases among those
putting together electrical meters.
Risk of mercurial poisoning is constantly present in _hatters’ furriers’
processes_ and in subsequent processes in felt hat factories. The risk
from use of nitrate of mercury is considerable to those brushing the
rabbit skins with the solution (carotting), and subsequently drying,
brushing, cutting, locking, and packing them. According to Hencke in
100 kilos of the carotting liquid there are 20 kilos of mercury. In
England, in the years 1899-1905, thirteen cases of mercurial poisoning
were reported in hatters’ furriers’ processes. Among eighty-one persons
so employed the medical inspector found twenty-seven with very defective
teeth as the result of the employment, and seventeen with marked tremor.
In the _manufacture of mercurial salts_ poisoning occurs chiefly when
they are made by sublimation, as in the manufacture of vermilion, of
corrosive sublimate (when mercurous sulphate is sublimed with salt), and
in the preparation of calomel (when sublimate ground with mercury or
mercurous sulphate mixed with mercury and salt is sublimed). Between 1899
and 1905 in England seven cases were reported from chemical works. As
to occurrence of mercury poisoning from _fulminate of mercury_, see the
chapter on Explosives.
ARSENIC
Chronic industrial _arsenical poisoning_, both as to origin and course,
is markedly different from the acute form.
The chronic form arises mainly from inhalation of minute quantities of
metallic arsenic or its compounds in recovery from the ore, or from the
use of arsenic compounds in the manufacture of colours, in tanyards, and
in glass making. Acute industrial _arseniuretted hydrogen poisoning_ is
especially likely to occur where metals and acids react on one another
and either the metal or the acid contains arsenic in appreciable amount.
Further, arseniuretted hydrogen may be contained in gases given off in
smelting operations and in chemical processes.
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