RECOVERY OF ARSENIC AND WHITE ARSENIC.—Pure arsenic is obtained from
native cobalt and arsenical pyrites by volatilisation on roasting the
ore in the absence of air. After the furnace has been charged sheet iron
condensing tubes are affixed to the mouths of the retorts, which project
out of the furnace, and to these again iron or earthenware prolongs.
Arsenic condenses on the sides of the sheet metal tubes and amorphous
arsenic, oxides, and sulphides in the prolongs. After sublimation has
been completed the contents of the prolongs are removed and used for
production of other arsenic compounds; the (generally) argentiferous
residues in the retorts are removed and further treated in silver
smelting works; finally, the crusts of crystalline arsenic (artificial
fly powder) are knocked out from the carefully unrolled sheet iron tubes.
As can be readily understood from the description opportunity of
poisoning from volatilisation of arsenic and of arsenic compounds is
considerable. Metallic arsenic is used for making hard shot, and for
increasing the brilliancy and hardness of metal alloys (type metal, &c.).
_White arsenic_ (arsenic trioxide) is obtained by roasting with access of
air in reverberatory furnaces arsenical ores and smelting residues. The
vapours of white arsenic sublime and are condensed as a powder in long
walled channels or in chambers, and are resublimed in iron cylinders.
White arsenic is used in making colours, in glass (for decolourising
purposes), as an insecticide in the stuffing of animals, &c.
INDUSTRIAL ARSENIC POISONING.—In the _extraction of arsenic_ and
preparation of arsenious acid danger is present. But reliable accounts in
literature of poisoning among those engaged in arsenic works are wanting.
Those engaged in roasting operations and packing suffer much from skin
affections. Similar poisoning is reported in the smelting of other
arsenical ores—nickel, cobalt, lead, copper, iron, and silver, from
arsenic compounds present in the fumes. This is especially the case in
the smelting of tin, which generally contains arsenical pyrites.
Danger is present also in _unhairing_ (i.e. removing the wool from sheep
skins), since the skins imported from Buenos Aires and Monte Video are
treated with a preservative which, in addition to sodium nitrate, soda,
and potash, contains generally arsenious acid.
In _tanneries_ a mixture of arsenic sulphide (realgar) and lime is used
for unhairing. Arsenic is used also for preserving and stuffing animal
furs; but although affections of the skin are described I cannot find
reference to arsenical poisoning.
The inspector for East London in 1905 refers to severe eczematous
eruptions on face, neck, and hands, affecting workers in a _sheep dip_
works—mainly in the packing of the light powder in packets.
Public-domain text, read in full here on John Shaqi.
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