A case is cited of a workman in Hamburg engaged in pulverising pure
antimony who was attacked with vomiting which lasted for several days,
and the inspector of factories noted epistaxis (nose bleeding) and
vomiting as following on the crushing of antimony ore.
Compositors in addition to chronic lead poisoning may suffer, it is
alleged, from chronic antimony poisoning, showing itself in diminution
in the number of white blood corpuscles and marked eosinophilia. These
changes in the blood could be brought about experimentally in rabbits.
Antimony was found by the Marsh test in the stools of those affected.
IRON
_Pig iron_ is obtained by smelting iron ores in blast furnaces (fig. 29),
through the upper opening of which charges of ore, limestone or similar
material to act as a flux, and coke are fed in succession. The furnaces
are worked continuously, using a blast of heated air; carbon monoxide is
produced and effects the reduction of the ore to molten iron. The latter
accumulates in the hearth and is covered with molten slag; this flows
constantly away through an opening and is collected in slag bogies for
removal, or is sometimes cooled in water.
The crude iron is tapped from time to time, and is led in a fluid
condition into moulds called ‘pigs,’ in which it solidifies. Cast iron is
occasionally used direct from the blast furnace for the purpose of making
rough castings, but generally it is further refined before being used in
a foundry by remelting with cast iron scrap in a cupola furnace.
[Illustration: FIG. 29.
_a_ Hearth; _b_ Bosh; _c_ Shaft; _d_ Gas uptake; _e_ Down-comer; _f_
Tuyères with water cooling arrangement; _g_ Blast pipes; _h_ Tapping
hole; _k_ Supporting columns; _l_ Furnace bottom; _m_ Charging hopper;
_n_ Bell with raising and lowering arrangement.]
_Wrought iron_ is made by treating pig iron in refinery and puddling
furnaces; in these much of the carbon is removed as carbon monoxide, and
from the puddling furnace the iron is obtained as a pasty mass which can
be worked into bars, rods, or plates.
_Steel_ is made in various ways. The Acid Bessemer process consists in
forcing compressed air in numerous small streams through molten cast
iron, in iron vessels (converters) which are lined with ganister, a
silicious sandstone. These can be rotated on trunnions. Basic Bessemer
steel is made in similar converters by the Thomas-Gilchrist or basic
process, which can be applied to pig irons containing phosphorus. The
latter is removed by giving the converter a basic lining of calcined
magnesium limestone mixed with tar.
In the _Martin_ process steel is obtained by melting together pig iron
with steel scrap, wrought iron scrap, &c., on the hearth of a Siemens
regenerative furnace with a silicious lining.
In iron smelting the most important danger is from _blast furnace
gas_ rich in carbonic oxide. Sulphur dioxide, hydrocyanic acid, and
arseniuretted hydrogen gas may possibly be present.
Public-domain text, read in full here on John Shaqi.
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