7. Evolution of poisonous gases is greatly increased by the
action of moisture, or of moist air, under the influence
of which phosphoretted hydrogen is generated from calcium
phosphide, which, in turn, is formed, in large part, at any
rate, from the calcium phosphate present in anthracite and
quartz, at the high temperature of the electric furnace. If
spontaneous disintegration of the alloy also occurs, much
larger quantities of gas would be given off from such friable
and unstable material, other conditions being equal. The
greater or less tendency of a given sample to evolve poisonous
gases, and even a rough estimate of their probable amount may
be arrived at by the use of test-papers prepared with silver
nitrate.
8. There is no evidence that low-grade ferro-silicon (10 to
15 per cent.), produced in the blast-furnace, has ever given
rise to accidents of similar character to those known to have
been caused by the high-grade electrically produced alloy.
Blast-furnace ferro-silicon does not evolve poisonous gases
even in presence of moisture.
9. As regards ferro-silicon produced in the electric furnace,
the evidence available goes to show that certain percentage
grades are practically quite innocuous. This statement applies
to grades of alloy of a silicon content up to and including
30 per cent., and probably also, though in considerably less
degree, to those of 70 per cent. and over.
10. In view of the fact that the use of ferro-silicon of grades
ranging between 30 per cent. and 70 per cent. apparently is
not essential in metallurgical operations, with the possible
exception of basic steel manufacture, it will be advisable that
the production of this alloy of grades ranging between these
percentages should be discontinued in the future.
11. The proprietors of iron and steel works making use
of ferro-silicon will assist in the protection of their
workpeople, and at the same time act for the public benefit by
restricting their orders to grades of this material, either
not exceeding 30 per cent., or of 70 per cent. and upwards,
according to the special nature of their requirements.
12. But as, pending international agreement on the question,
intermediate percentages of ferro-silicon will doubtless
continue to be manufactured and sold, the issue, by the Board
of Trade, of special regulations will be necessary in order to
obviate, so far as may be possible, chance of further accidents
during the transport of this substance.
_Inter alia_, these regulations should require a declaration
of the nature, percentage, date of manufacture, and place of
origin of any such consignment.
The suggested regulations are printed on p. 291.]
ZINC
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