[In January 1905 fifty steerage passengers were made seriously ill and
eleven of them died. In 1907 five passengers died on a Swedish steamer
as the result of poisonous gases given off from ferro-silicon, and
more recently five lives were lost on the steamer _Aston_ carrying
the material from Antwerp to Grimsby.[C] This accident led to full
investigation of the subject by Dr. Copeman, F.R.S., one of the Medical
Inspectors of the Local Government Board, Mr. S. R. Bennett, one of H.M.
Inspectors of Factories, and Dr. Wilson Hake, Ph.D., F.I.C., in which the
conclusions arrived at are summarised as follows:
1. Numerous accidents, fatal and otherwise, have been caused
within the last few years by the escape of poisonous and
explosive gases from consignments of ferro-silicon, which,
in every instance, have been found to consist of so-called
high-grade ferro-silicon, produced in the electric furnace.
2. These accidents, for the most part, have occurred during
transport of the ferro-silicon by water, whether in sea-going
vessels or in barges and canal-boats plying on inland waters.
3. These accidents have occurred in various countries and on
vessels of different nationalities, while the ferro-silicon
carried has, in almost every instance, been the product of a
different manufactory.
4. Ferro-silicon, especially of grades containing from 40 per
cent. to 60 per cent. of silicon, is invariably found to evolve
considerable quantities of phosphoretted hydrogen gas, and, in
less amount, of arseniuretted hydrogen, both of which are of a
highly poisonous nature. A certain amount of the gas evolved
is present, as such, in the alloy, being ‘occluded’ in minute
spaces with which its substance is often permeated.
5. As the result of careful investigation, it has been
shown that certain grades of ferro-silicon—notably such as
contain about 33 per cent., 50 per cent., and 60 per cent. of
silicon—even when manufactured from fairly pure constituents,
are both brittle and liable to disintegrate spontaneously, this
latter characteristic being apt to be specially marked in the
case of the 50 per cent. grade.
All these grades are commonly employed at the present time.
6. In the event of disintegration occurring, the amount of
surface exposed will, obviously, be greater than if the mass
were solid.
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