Oxychloride of carbon (COCl₂), also called phosgene, is, at the ordinary
temperature, a colourless gas with a disagreeable smell. This decomposes
in moist air into carbonic oxide, hydrochloric acid, or chlorine, and
produces a strongly irritant local effect upon the mucous membranes.
Industrial poisoning by phosgene is characterised by great difficulty
in breathing and inflammation of the respiratory tract (bronchitis and
bloodstained expectoration).
Several cases have been treated successfully by oxygen inhalation.
NICKEL CARBONYL
The effects of nickel carbonyl are described on pp. 186-8.
CARBONIC ACID
Carbonic acid (CO₂), a colourless gas, is heavier than air (specific
weight, 1·526), and therefore, wherever it collects, sinks to the ground.
Carbonic acid is only very slightly poisonous; about 10 per cent.
carbonic acid in the air causes asphyxia. The extinguishing of a candle
flame will serve as an indication that the amount of carbonic acid in
the atmosphere has reached this point. Cases of industrial carbonic acid
asphyxia are sudden; they do not occur frequently.
The gradual action of the gas when mixed with air produces first a
tingling sensation on the surface of the body, reddening of the face,
irritation of the mucous membrane and the respiratory organs, after
which succeed difficulty in breathing, palpitation, fainting, and
unconsciousness.
Sudden and fatal poisoning occurs industrially. Upon entering places
filled with carbonic acid gas the affected person falls down dead almost
immediately. These are cases of asphyxia, in which the lack of oxygen
certainly plays the greatest part. If those affected by acute carbonic
acid poisoning are removed in time out of the dangerous atmosphere they
usually recover quickly.
Oxygen inhalations and artificial respiration are to be applied in
severer cases. There are no sequelæ.
_GROUP: HYDROCARBONS OF THE ALIPHATIC AND AROMATIC SERIES AND THEIR
HALOGEN AND HYDROXYL SUBSTITUTION PRODUCTS_
The industrial poisons comprised in this group have as their principal
general effect injurious action upon the functions of the central
nervous system (paralysis or causing excitation) which is prominent in
most of the cases of industrial poisoning caused by these substances.
This effect is most marked in the case of the readily volatile (low
boiling) hydrocarbons, while those less volatile and boiling at a higher
temperature often have collateral effects (such as local irritation).
The characteristic poisonous effect caused by the chlorine and
hydroxyl-substitution products (chloroform and alcohol group) is also
mainly on the central nervous system (narcosis).
HYDROCARBONS OF MINERAL OIL
BENZINE, LIGROINE, PETROLEUM, PARAFFIN, VASELINE
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