Further, the lead burners and plumbers are exposed to the danger of
chronic lead poisoning from insufficient observance of the personal
precautionary measures necessary to guard against it (see Part III).
Those who are constantly engaged in burning the lead sheets and pipes of
the chambers suffer not infrequently from severe symptoms. Unfortunately,
the work requires skill and experience, and hence alternation of
employment is hardly possible.
Finally, mention should be made of poisoning by _arseniuretted hydrogen
gas_ from vessels filled with sulphuric acid containing arsenic as an
impurity, and by sulphuretted hydrogen gas in purifying the acid itself.
In the manufacture of liquid _sulphur dioxide_, injury to health can
arise from inhalation of the acid escaping from the apparatus. The most
frequent cause for such escape of sulphur dioxide is erosion of the walls
of the compressor pumps and of the transport vessels, in consequence of
the gas being insufficiently dried, as, when moist, it attacks iron.
Sulphur dioxide will come up for further consideration when describing
the industrial processes giving rise to it, or in which it is used.
HYDROCHLORIC ACID, SALTCAKE, AND SODA
MANUFACTURE.—The production of hydrochloric acid (HCl), sodium sulphate
(Na₂SO₄), and sodium sulphide (Na₂S) forms part of the manufacture of
soda (Na₂CO₃) by the Leblanc process. The products first named increase
in importance, while the Leblanc soda process is being replaced more and
more by the manufacture of soda by the Solvay ammonia process, so much so
that on the Continent the latter method predominates and only in England
does the Leblanc process hold its ground.
Health interests have exercised an important bearing on the development
of the industries in question. At first, in the Leblanc process the
hydrochloric acid gas was allowed to escape into the atmosphere, being
regarded as a useless bye-product. Its destructive action on plant
life and the inconvenience caused to the neighbourhood, in spite of
erection of high chimneys, demanded intervention. In England the evils
led to the enactment of the Alkali Acts—the oldest classical legislative
measures bearing on factory hygiene—by which the Leblanc factories were
required to condense the vapour by means of its absorption in water, and
this solution of the acid is now a highly valued product. And, again,
production of nuisance—inconvenience to the neighbourhood through the
soda waste—was the main cause of ousting one of the oldest and most
generally used methods of chemical industrial production. Although every
effort was made to overcome the difficulties, the old classical Leblanc
process is gradually but surely yielding place to the modern Solvay
process, which has no drawback on grounds of health.
We outline next the main features of the _Leblanc soda process_, which
includes, as has been mentioned, also the manufacture of hydrochloric
acid, sodium sulphate and sulphide.
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