Very unpleasant yellow fumes develop in great quantity when pitch is run
off from the hot still. Hence hot pitch should not be run off into open
pitch receptacles, but be cooled first in closed receptacles.
The crude products obtained by distillation (light oil, creosote oil)
are subjected to purification consisting in treatment on the one hand
with alkali and on the other with acid and followed by fractional
distillation. In these processes injurious fumes may develop, therefore
they must—as already mentioned—be carried on in closed vessels provided
with means of escape for fumes and appliances for mechanical stirring;
the fumes drawn off must be led into the chimney stack.
In the distillation of brown coal, of tar, and of resin, it is necessary,
as in the distillation of coal tar, to insist above all on careful
cooling and condensation, and thorough absorption of uncondensed gases
in washing towers. Special precautionary rules are necessary to guard
against the danger of entering tar stills for cleaning purposes. Such
directions were approved in Great Britain in 1904 in view of accidents
which occurred in this way:
TAR DISTILLING
The following directions[I] are approved by the Home Office
and are applicable to factories in which is carried on the
distillation of tar for the production of naphtha, light oil,
creosote oil, and pitch.
1. During the process of cleaning, every tar still should
be completely isolated from adjoining tar stills either by
disconnecting the pipe leading from the swan neck to the
condenser worm, or by disconnecting the waste gas pipe fixed
to the worm end or receiver. Blank flanges should be inserted
between the disconnections. In addition, the pit discharge pipe
or cock at the bottom of the still should be disconnected.
2. Every tar still should be ventilated and allowed to cool
before persons are allowed to enter.
3. Every tar still should be inspected by the foreman or other
responsible person before any workman is allowed to enter.
4. The inspecting foreman on first entering any tar still
or tank, and all persons employed in tar stills or tanks in
which there are no cross stays or obstructions likely to cause
entanglement, should be provided with a belt securely fastened
round the body with a rope attached, the free end being left
with two men outside whose sole duty should be to watch and
draw out any person appearing to be affected by gas. The belt
and rope should be adjusted and worn in such a manner that the
wearer can be drawn up head foremost and through the manhole
and not across it.
Public-domain text, read in full here on John Shaqi.
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