Care must be taken for the removal of injurious gases developed in the
manipulation and use of tar (tar distillation) and in the processes
of cleaning connected therewith. This can be most effectively done by
carrying on the processes in closed apparatus. Hofmann describes such
a factory where all mixing vessels in which the distillation products
are further treated are completely closed in, so that even in mixing and
running off, no contact is possible with the material.
The vessels for holding tar, tar-water, &c., must be impervious and
kept covered. Only the cold pitch and asphalt should be stored in open
pits. The cooling of the distillation products and residues, so long as
they give off poisonous and strongly-smelling fumes, should be carried
out in metal or bricked receivers. Such directions find a place in the
‘Technical Instructions’ appended to the German Factory Code. Without
doubt, tar is, because of its smell and for other reasons, unpleasant to
handle, and the danger to health from contact with it is not a matter
of indifference. Spilling of small quantities of tar during transport
and other manipulations can hardly be avoided. Careful cleanliness,
therefore, on the part of workers is strongly urged. It may be mentioned
that if tar is covered with a layer of tar-water, treatment with acid
fluids develops sulphur and cyanogen compounds, which may affect the
workers. Tar water should, therefore, be separated carefully from the tar
and used for the preparation of ammonia.
The same remarks as to cleanliness, &c., apply in the manufacture of
felt, lamp-black, and briquettes, with use of tar. Saturation of felt,
and manufacture of tar plaster should be done in closed apparatus.
In the production of lamp-black, even with a great number of soot
chambers, there is escape of soot causing nuisance to workers and the
neighbourhood. Complete avoidance of this seems to be difficult, so that
measures for personal hygiene must be assured. In briquette factories it
has been found useful to heat the tar by means of steam instead of by
direct fire, which renders possible the use of a closed apparatus and
mechanical stirring.
In the distillation of tar, during the first distillation period (first
runnings) unpleasant and injurious gases containing ammonia and sulphur
escape from the stills. These should (according to Leymann) be carried
away through closed pipes branching off from the lower end of the
running-off pipe, either into the furnace (in doing which a possible back
flash of flame is to be guarded against) or be subjected to purification
by lime or oxide of iron (similar to that in the case of illuminating
gas) with a view to recovery of ammonia and sulphur. The lower end of the
distillation pipes should be U-shaped so as to form a liquid seal—the
pipes for the drawing off of the gases branching off before the curve. In
the later stages of distillation risk can be checked by careful cooling
and imperviousness of the apparatus.
Public-domain text, read in full here on John Shaqi.
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