The gases are led each through earthenware pipes or channels of stone
pickled with tar (A´), first into small towers of Yorkshire flags (B),
where they are cooled and freed from flue dust and impurities (sulphuric
acid) by washing. They are next led through a series (over fifty) of
Woulff bottles (bombonnes) one metre high, made of acid-resisting
stoneware. The series is laid with a slight inclination towards the
furnace, and water trickles through so that the gases coming from the
wash towers are brought into contact with water in the one case already
almost saturated, whilst the gas which is poorest in hydrochloric acid
meets with fresh water. From the bombonne situated next to the wash tower
the prepared acid is passed as a rule through another series. The last
traces of hydrochloric acid are then removed by leading the gases from
the Woulff bottles up two water towers of stoneware (D and E), which are
filled partly with earthenware trays and partly with coke; above are
tanks from which the water trickles down over the coke. The residual
gases from both sets of absorbing apparatus now unite in a large Woulff
bottle before finally being led away through a duct to the chimney stack.
Less frequently absorption of hydrochloric acid is effected without use
of Woulff bottles, principally in wash towers such as the Lunge-Rohrmann
plate tower.
In the purification of hydrochloric acid, de-arsenicating by sulphuretted
hydrogen or by barium sulphide, &c., and separation of sulphuric acid by
addition of barium chloride, have to be considered.
Another method for production of sulphate and hydrochloric acid, namely,
the Hargreaves process, is referred to later.
We return now to the further working up of the sodium sulphate into
sulphide and soda. The conversion of the sulphate into soda by the
Leblanc method is effected by heating with coal and calcium carbonate,
whereby, through the action of the coal, sodium sulphide forms first,
which next with the calcium carbonate becomes converted into sodium
carbonate and calcium sulphide.
The reactions are:
Na₂SO₄ + 2C = Na₂S + 2CO₂
Na₂S + CaCO₃ = Na₂CO₃ + CaS
CaCO₃ + C = CaO + 2CO.
The reactions are carried out in small works in open reverberatory
furnaces having two platforms on the hearth, and with continuous raking
from one to the other which, as the equations show, cause escape of
carbonic acid gas and carbonic oxide.
Such handworked furnaces, apart from their drawbacks on health grounds,
have only a small capacity, and in large works their place is taken by
revolving furnaces—closed, movable cylindrical furnaces—in which handwork
is replaced by the mechanical revolution of the furnace and from which a
considerably larger output and a product throughout good in quality are
obtained.
Public-domain text, read in full here on John Shaqi.
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