In the manufacture of bleaching powder from Deacon chlorine, Hasenclever
has constructed a special cylindrical apparatus (fig. 8), consisting of
several superimposed cast-iron cylinders in which are worm arrangements
carrying the lime along, while chlorine gas passes over in an opposite
direction. This continuous process is, however, only possible for the
Deacon chlorine strongly diluted with nitrogen and oxygen and not for
undiluted Weldon gas.
_Liquid chlorine_ can be obtained by pressure and cooling from
concentrated almost pure Weldon chlorine gas.
_Potassium chlorate_, which, as has been said, is now mostly obtained
electrolytically, was formerly obtained by passing Deacon chlorine into
milk of lime and decomposing the calcium chlorate formed by potassium
chloride.
Chlorine and chloride of lime are used for bleaching; chlorine further
is used in the manufacture of colours; chloride of lime as a mordant in
cloth printing and in the preparation of chloroform; the chlorates are
oxidising agents and used in making safety matches. The manufacture of
organic chlorine products will be dealt with later.
[Illustration: FIG. 8.—Preparation of Bleaching Powder. Apparatus of
Hasenclever (_after Ost_)
A Hopper for slaked lime; W Worm conveying lime; Z Toothed wheels;
K Movable covers; C Entrance for chlorine gas; D Pipe for escape of
chlorine-free gas; B Outlet shoot for bleaching powder]
EFFECTS ON HEALTH.—In these industries the possibility of injury to
health and poisoning by inhalation of chlorine gas is prominent. Leymann
has shown that persons employed in the manufacture of chlorine and
bleaching powder suffer from diseases of the respiratory organs 17·8 per
cent., as contrasted with 8·8 per cent. in other workers: and this is
without doubt attributable to the injurious effect of chlorine gas, which
it is hardly possible to avoid despite the fact that Leymann’s figures
refer to a model factory. But the figures show also that as the industry
became perfected the number of cases of sickness steadily diminished.
Most cases occur from unsatisfactory conditions in the production of
chloride of lime, especially if the chloride of lime chambers leak, if
the lime is turned over while the chlorine is being let in, by too early
entrance into chambers insufficiently ventilated, and by careless and
unsuitable methods of emptying the finished bleaching powder.
The possibility of injury is naturally greater from the concentrated gas
prepared by the Weldon process than from the diluted gas of the Deacon
process—the more so as in the latter the bleaching powder is made in
the Hasenclever closed-in cylindrical apparatus in which the chlorine
is completely taken up by the lime. The safest process of all is the
electrolytic, as, if properly arranged, there should be no escape of
chlorine gas. The chlorine developed in the cells (when carried out on
the large scale) is drawn away by fans and conducted in closed pipes to
the place where it is used.
Public-domain text, read in full here on John Shaqi.
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